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Abstract
Due to their pronounced bioactivity and limited availability from natural resources, metabolites of the soft coral Pseudopterogorgia elisabethae, such as erogorgiaene and the pseudopterosines, represent important target molecules for chemical synthesis. We have now developed a particularly short and efficient route towards these marine diterpenes exploiting an operationally convenient enantioselective cobalt‐catalyzed hydrovinylation as the chirogenic step. Other noteworthy C−C bond forming transformations include diastereoselective Lewis acid‐mediated cyclizations, a Suzuki coupling and a carbonyl ene reaction. Starting from 4‐methyl‐styrene the anti‐tubercular agent (+)‐erogorgiaene (>98 % ee) was prepared in only 7 steps with 46 % overall yield. In addition, the synthesis of the pseudopterosin A aglycone was achieved in 12 steps with 30 % overall yield and, surprisingly, was found to exhibit a similar anti‐inflammatory activity (inhibition of LPS‐induced NF‐κB activation) as a natural mixture of pseudopterosins A−D or iso‐pseudopterosin A, prepared by β‐D‐xylosylation of the synthetic aglycone.
AbstractThis paper discusses the comparison of two methods to achieve thermal comfort utilising air conditioning (AC) system in a small indoor space – adaptive control and fuzzy control. Thermal comfort indoors is performed to provide comfortability individually or for a group of people. Due to the small indoor space which usually a bit cramped, crowded and less airy, the ambience can be very uncomfortable either for doing sedentary or active work, thus the AC system can be very useful to provide thermal comfort. Both methods can be utilised depending on how thermal comfort is viewed and how the level of thermal comfort is decided. Every method has its own advantage and limitations, and will be covered in this paper as well.
Table Tennis Tutor: Forehand Strokes Classification Based on Multimodal Data and Neural Networks
(2021)
Beginner table-tennis players require constant real-time feedback while learning the fundamental techniques. However, due to various constraints such as the mentor’s inability to be around all the time, expensive sensors and equipment for sports training, beginners are unable to get the immediate real-time feedback they need during training. Sensors have been widely used to train beginners and novices for various skills development, including psychomotor skills. Sensors enable the collection of multimodal data which can be utilised with machine learning to classify training mistakes, give feedback, and further improve the learning outcomes. In this paper, we introduce the Table Tennis Tutor (T3), a multi-sensor system consisting of a smartphone device with its built-in sensors for collecting motion data and a Microsoft Kinect for tracking body position. We focused on the forehand stroke mistake detection. We collected a dataset recording an experienced table tennis player performing 260 short forehand strokes (correct) and mimicking 250 long forehand strokes (mistake). We analysed and annotated the multimodal data for training a recurrent neural network that classifies correct and incorrect strokes. To investigate the accuracy level of the aforementioned sensors, three combinations were validated in this study: smartphone sensors only, the Kinect only, and both devices combined. The results of the study show that smartphone sensors alone perform sub-par than the Kinect, but similar with better precision together with the Kinect. To further strengthen T3’s potential for training, an expert interview session was held virtually with a table tennis coach to investigate the coach’s perception of having a real-time feedback system to assist beginners during training sessions. The outcome of the interview shows positive expectations and provided more inputs that can be beneficial for the future implementations of the T3.
Linoleic acid hydroperoxides are versatile intermediates for the production of green note aroma compounds and bifunctional ω-oxo-acids. An enzyme cascade consisting of lipoxygenase, lipase and catalase was developed for one-pot synthesis of 13-hydroperoxyoctadecadienoic acid starting from safflower oil. Reaction conditions were optimized for hydroperoxidation using lipoxygenase 1 from Glycine max (LOX-1) in a solvent-free system. The addition of green surfactant Triton CG-110 improved the reaction more than two-fold and yields of >50% were obtained at linoleic acid concentrations up to 100 mM. To combine hydroperoxidation and oil hydrolysis, 12 lipases were screened for safflower oil hydrolysis under the reaction conditions optimized for LOX-1. Lipases from Candida rugosa and Pseudomonas fluorescens were able to hydrolyze safflower oil to >75% within 5 h at a pH of 8.0. In contrast to C. rugosa lipase, the enzyme from P. fluorescens did not exhibit a lag phase. Combination of P. fluorescens lipase and LOX-1 worked well upon LOX-1 dosage and a synergistic effect was observed leading to >80% of hydroperoxides. Catalase from Micrococcus lysodeikticus was used for in-situ oxygen production with continuous H2O2 dosage in the LOX-1/lipase reaction system. Foam generation was significantly reduced in the 3-enzyme cascade in comparison to the aerated reaction system. Safflower oil concentration was increased up to 300 mM linoleic acid equivalent and 13-hydroperoxides could be produced in a yield of 70 g/L and a regioselectivity of 90% within 7 h.
The majority of Niger ’s population faces a widespread lack of access to electricity. Althoughthe country lies in the Sahara belt, exploitation of solar energy is so far minimal. Due to ongoing fossilfuel exploration in the country, this fuel might dominate the future electricity supply. Today, Nigerimports the most of its electricity from Nigeria. There is a need to expand electricity generation andsupply infrastructures in Niger. When doing so, it is important to choose a proper set of electricitygeneration resource/technology that fulfils sustainability criteria. Thus, the objective of this work isto analyze a methodology in order to assess different energy technologies for Niger. A multi-criteriadecision approach was selected to assess the most accessible energy system for the country. Forthis purpose, indicators were developed and weighted for ranking electricity generation options.Altogether 40 indicators are selected under six dimensions (availability, risk, technology, economics,environment and social) to assess eight different alternatives, considering the aggregated results andcorresponding scores under each dimension. A merit list of technology and resources for electricitygeneration presented in this work could support the stakeholders in their decision-making for furtherprojects implementation in the country.
Due to reasons of sustainability and conservation of resources, polyurethane (PU)-based systems with preferably neutral carbon footprints are in increased focus of research and development. The proper design and development of bio-based polyols are of particular interest since such polyols may have special property profiles that allow the novel products to enter new applications. Sophorolipids (SL) represent a bio-based toolbox for polyol building blocks to yield diverse chemical products. For a reasonable evaluation of the potential for PU chemistry, however, further investigations in terms of synthesis, derivatization, reproducibility, and reactivity towards isocyanates are required. It was demonstrated that SL can act as crosslinker or as plasticizer in PU systems depending on employed stoichiometry. (ω-1)-hydroxyl fatty acids can be derived from SL and converted successively to polyester polyols and PU. Additionally, (ω-1)-hydroxyl fatty acid azides can be prepared indirectly from SL and converted to A/B type PU by Curtius rearrangement.
Remote rural populations do not often have the luxury of viable multisource electricity generation systems. Considering fossil fuels for remote populated areas is not often a viable option due to the fuel transportation costs and the population’s socioeconomic status. Extending the grid is often economically prohibitive. This paper proposes possible ways in which Mali could increase the rate of population with access to electricity by 2050 using Low Emission Analysis Platform (LEAP) and geographical information tools. The current energy situation is assessed, and multiple demand and supply scenarios are created to find the most viable option in environmental and economic dimensions. A minimum of 50% reduction of biomass consumption in the residential sector and a maximum of 71% was achieved through the combination of grid extension and decentralized solar PV. Solar PV becomes the preferable option when enough time for the effects of electricity on income is given. When these effects are not present, solar PV is still a better option, as the amount of biomass replaced with electricity is reduced.
In the last decade, the utilization of waste by-product apple pomace has been extensively researched (due to its difficult disposal) and currently finds beneficial usage in various industries; as substrate for microbial growth or recovery of pectin, xyloglucan and polyphenols. In this research apple juice was produced at pilot scale. Furthermore, apple pomace was employed as substrate for the production of pectin, biofuel (pellets) and concentrated apple pomace extract. Extensive mass and heat balances were conducted to evaluate the feasibility of this approach on industrial scale. The produced pellets had very similar characteristics to wood pellets (net calorific value of 20.3 MJ/kg). Dried apple pomace contained 11.9% of pectin. Fed-batch cultivation of baker´s yeast with apple pomace extract demonstrated a potential for partial substitution of molasses in industrial bioprocesses. This concept shows how a zero discharge biorefinery process converts waste from apple juice production into three valuable products enabling connections between different industries.
Different methods have been proposed for in situ root-length density (RLD) measurement. One widely employed is the time-consuming sampling of soil cores or monoliths (MO). The profile wall (PW) method is a less precise, but faster and less laborious alternative. However, depth-differentiated functions to convert PW RLD estimates to MO RLD measurements have not yet been reported. In this study, we perform a regression analysis to relate PW results to MO results and determine whether calibration is possible for distinct crop groups (grasses, brassicas and legumes) consisting of pure and mixed stands, and whether soil depth affects this calibration. The methods were applied over two years to all crop groups and their absolute and cumulative RLD were compared using a linear (LR) and multiple linear (MLR) regression. PW RLD was found to highly underestimate MO RLD in absolute values and in highly rooted areas. However, a close agreement between both methods was found for cumulative root-length (RL) when applying MLR, highlighting the influence of soil depth. The level of agreement between methods varied strongly with depth. Therefore, the application of PW as the main RLD estimation method can provide reliable estimates of cumulative root distribution traits of cover crops.
This paper studies the process of business cycle synchronization in the European Union and the euro area. As our baseline methodology we adopt rolling window correlation coefficients of various economic indicators, observed since 2000. Among the indicators, we distinguish between real economic indicators, like the real GDP growth and unemployment, and nominal indicators, like inflation and government budget. Given the direct implication of this kind of analysis for the common monetary policy of the European Central Bank (ECB), special attention is paid to the pattern of business cycle synchronization in the core and peripheral members of the euro area. Our analysis of quarterly data covering the first two decades of the euro area shows that there was a certain synchronization tendency in the first years of the common currency. However, the European debt crisis halted the economic integration within the European Union and—even more so—within the euro area. Since the ECB can to a large extent intervene only with “one-size-fits-all” monetary policy instruments, this renders increasingly cumbersome the conduct of stabilisation policies within the euro area.
Ten female and five male participants (age range 28–50 years) were recruited at esoteric fairs or via esoteric chatrooms. In a guided face-to-face interview, they reported origins and contents of their beliefs in e.g. esoteric practices, supernatural beings, rebirthing, channeling. Transcripts of the tape-recorded reports were subjected to a qualitative analysis. Exhaustive categorization of the narratives’ content revealed that paranormal beliefs were functional with regard to two fundamental motives – striving for mastery and valuing me and mine (striving for a positive evaluation of the self). Moreover, paranormal beliefs paved the way for goal-setting and leading a meaningful life but, on the negative side, could also result in social exclusion. Results are discussed with reference to the adaptive value of paranormal beliefs.
Pluvial floods claimed more than 180 lives in Germany in July 2021, when a large and slow-moving storm system affected Germany and many neighbouring countries. The death tolls and damages were the highest since 1962 in Germany, and soon after, the crisis management was under public critique. This study has undertaken an online survey to understand crisis management better and identify lessons to learn. It has received a positive interest among operational relief forces and other helpers (n = 2264). The findings reveal an overall satisfaction with the operation in general as well as personal lessons learned. It also reveals shortcomings in many areas, ranging from information distribution, coordination, parallel ongoing COVID-19 pandemic, infrastructure resilience, and other factors. Just as well, areas for improvement of the crisis management system are suggested by the respondents. Cooperation and support by the affected population are perceived as positive. This helps to inform other areas of research that are necessary, such as studies on the perception by the affected people. The gaps in assessments of operational forces and some methodological constraints are discussed to advance future follow-up studies.
Currently, difficulties such as the depletion of fossil fuel resources and the associated environmental pollution have driven the rise of other energy systems based on green energy sources.
In this research, modeling and a viability study of grid-connected and islanded photovoltaic (PV) power systems for supplying the residential load in Mekelle City, Ethiopia, were carried out considering the country’s emerging utility tariff plan for 2021 and beyond. The technical viability of the proposed supply option was analyzed using PVGIS, PVWatts and HOMER Pro tool, while the economic and environmental optimization aspects were carried out using HOMER Pro. Sensitivity analyses and output comparisons among the three renewable energy simulation tools are presented.
The results showed that under the consideration of an incremental electricity tariff plan (up to 2021), the analyzed cost of energy of the grid/PV system is around 12% lower than the utility grid tariff. Moreover, we also found that by taking the continuous global solar PV cost reduction into account, the cost of energy of the modeled islanded operation of solar PV power units totally broke the grid tariff in Ethiopia after 2029 based on the tariff for 2021 and well before with the expected escalation of the grid tariff on an annual basis. The technical performance of the system realized through PVGIS and PVWatts was almost comparable to the HOMER Pro outputs. Thus, this investigation will offer a clear direction to the concerned target groups and policy developers in the evolution of PV power supply options throughout the technically viable locations in the country.
The production of pharmaceutical ingredients, intermediates and final products strongly depends on the utilization of water. Water is also required for the purification and preparation of reagents. Each specific application determines the respective water quality. In the European Union, the European Pharmacopeia (Ph. Eur.) contains the official standards that assure quality control of pharmaceutical products during their life cycle. According to this, the production of water for pharmaceutical use is mainly based on multi-stage distillation and membrane processes, especially, reverse osmosis. Membrane distillation (MD) could be an alternative process to these classical methods. It offers advantages in terms of energy demand and a compact apparatus design. In the following study, the preparation of pharmaceutical-grade water from tap water in a one-step process using MD is presented. Special emphasis is placed on the performance of two different module designs and on the selection of optimum process parameters.
This paper introduces a Business Cycle Indicator to compile a transparent and reliable chronology of past business cycle turning points for Germany. The Indicator is derived applying the statistical method of Principal Component Analysis, based on information from 20 economic time series. In this way, the Business Cycle Indicator grasps the development of the broader economic activity and has several advantages over a business cycle assessment based on quarterly series of Gross Domestic Product.
Hydrogen is nowadays in focus as an energy carrier that is locally emission free. Especiallyin combination with fuel-cells, hydrogen offers the possibility of a CO2neutral mobility, providedthat the hydrogen is produced with renewable energy. Structural parts of automotive componentsare often made of steel, but unfortunately they may show degradation of the mechanical propertieswhen in contact with hydrogen. Under certain service conditions, hydrogen uptake into the appliedmaterial can occur. To ensure a safe operation of automotive components, it is therefore necessary toinvestigate the time, temperature and pressure dependent hydrogen uptake of certain steels, e.g., todeduct suitable testing concepts that also consider a long term service application. To investigate thematerial dependent hydrogen uptake, a tubular autoclave was set-up. The underlying paper describesthe set-up of this autoclave that can be pressurised up to 20 MPa at room temperature and can beheated up to a temperature of 250◦C, due to an externally applied heating sleeve. The second focusof the paper is the investigation of the pressure dependent hydrogen solubility of the martensiticstainless steel 1.4418. The autoclave offers a very fast insertion and exertion of samples and thereforehas significant advantages compared to commonly larger autoclaves. Results of hydrogen chargingexperiments are presented, that were conducted on the Nickel-martensitic stainless steel 1.4418.Cylindrical samples 3 mm in diameter and 10 mm in length were hydrogen charged within theautoclave and subsequently measured using thermal desorption spectroscopy (TDS). The resultsshow how hydrogen sorption curves can be effectively collected to investigate its dependence ontime, temperature and hydrogen pressure, thus enabling, e.g., the deduction of hydrogen diffusioncoefficients and hydrogen pre-charging concepts for material testing.
A test tool for Langton's ant-based algorithms is created. Among other things, it can create test files for the NIST-Statistical-Test-Suite. The test tool is used to investigate the invertibility, ring formation and randomness of 7 created models which are extensions of Langton’s ant. The models are examined to possibly use them as pseudo-random generator (PRG) or block cipher. All models use memories which are based on tori. This property is central, because this is how rings are formed in the first place and in addition the behavior of all models at the physical boundaries of the memory is clearly defined in this way. The different models have special properties which are also investigated. These include variable color sets, discrete convolution, multidimensionality, and the use of multiple ants, which are arranged fractal hierarchically and influence each other. The extensions convolution, multidimensional scalable and multidimensional scalable fractal ant colony are presented here for the first time. It is shown that well-chosen color sets and high-dimensional tori are particularly well suited as a basis for Langton's ant based PRGs. In addition, it is shown that a block cipher can be generated on this basis.
In Latin America and the Caribbean, river restoration projects are increasing, but many lack strategic planning and monitoring. We tested the applicability of a rapid visual social–ecological stream assessment method for restoration planning, complemented by a citizen survey on perceptions and uses of blue and green infrastructure. We applied the method at three urban streams in Jarabacoa (Dominican Republic) to identify and prioritize preferred areas for nature-based solutions. The method provides spatially explicit information for strategic river restoration planning, and its efficiency makes it suitable for use in data-poor contexts. It identifies well-preserved, moderately altered, and critically impaired areas regarding their hydromorphological and socio-cultural conditions, as well as demands on green and blue infrastructure. The transferability of the method can be improved by defining reference states for assessing the hydromorphology of tropical rivers, refining socio-cultural parameters to better address river services and widespread urban challenges, and balancing trade-offs between ecological and social restoration goals.
Abstract
In the chemical industry large amounts of saline wastewater occur. Its disposal into rivers is a considerable burden to the ecosystem. To strive for a circular economy and enable a viable raw material recycling, energy‐efficient concentration processes are requisite. High‐pressure reverse osmosis meets this criterion, but its industrial application demands suitable membrane elements that withstand the exceptional operation conditions and provide sufficient performance. Hence, new requirements regarding the design of spiral‐wound elements arise. To identify those, specific performance‐limiting effects need a better understanding.
Floods are a known natural hazard in Germany, but the amount of precipitation and ensuing high death toll and damages after the events especially from 14 to 15 July 2021 came as a surprise. Almost immediately questions about failure in the early warning chains and the effectiveness of the German response emerged, also internationally. This article presents lessons to learn and argues against a blame culture. The findings are based on comparisons with findings from previous research projects carried out in the Rhein-Erft Kreis and the city of Cologne, as well as on discussions with operational relief forces after the 2021 events. The main disaster aspects of the 2021 flood are related to issuing and understanding warnings, a lack of information and data exchange, unfolding upon a situation of an ongoing pandemic and aggravated further by critical infrastructure failure. Increasing frequencies of flash floods and other extremes due to climate change are just one side of the transformation and challenge, Germany and neighbouring countries are facing. The vulnerability paradox also heavily contributes to it; German society became increasingly vulnerable to failure due to an increased dependency on its infrastructure and emergency system, and the ensuing expectations of the public for a perfect system.