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This is the fifth time that TH Köln has conducted this study to examine the local XR industry´on behalf of Mediencluster NRW GmbH, a subsidiary of Film- und Medienstiftung NRW. Aside from the two surveys on the North Rhine-Westphalian sector, there have now been three studies on the nationwide XR (extended or cross reality) sector in Germany. By this we mean all companies that create products and services in the field of virtual, mixed or augmented reality (but not firms that employ XR as users).
Decisions on irrigation water management are usually made at different levels, including farms, water user associations (WUAs), and regional water planning agencies. The latter generally have good access to information and decision tools regarding water resources management. However, these remain out of reach to the final water users, namely the farmers. The study, conducted in the irrigated district of Cherfech, north Tunisia, had the main objective of investigating farmer’s perceptions of, and acceptance for, the use of an irrigation advisory service (IAS) to be implemented by their WUA. The suggested IAS provides the following information: (1) reference evapotranspiration (ETo) and rainfall; (2) crop water requirement (CWR) of the most cultivated crops; (3) irrigation water requirement (IWR) of the farmer’s crop; and (4) crop monitoring and real-time estimation of IWR of crops settled, using soil moisture sensors. Such services and information would be available at the WUA level and provided in a timely manner to farmers for more effective decision making at the plot level. Prior to the acceptance study, we launched a technical study to determine the required tools and equipment required for the implementation of the IAS, followed by a farmer survey to assess their respective perceptions and acceptance towards this IAS. Results showed that only 54% of the farmers are satisfied by WUAs work, but that 77% of them accepted using the suggested IAS. Farmers are also willing to pay for most of the IAS packages suggested. The financial profitability of investing in the IAS at the WUA level shows the venture is financially viable, with a benefit cost ratio (BCR) of 1.018. The project will be even more profitable if we add the social benefits, which may result in water savings at the WUA level.
The importance of lithium as a raw material is steadily increasing, especially in the growing markets of grid energy and e-mobility. Today, brines are the most important lithium sources. The rising lithium demand raises concerns over the expandability and the environmental impact of common mining techniques, which are mainly based on the evaporation of brine solutions (Salars) in arid and semiarid areas. In this case, much of the water contained in the brine is lost. Purification processes lead to further water losses of the ecosystems. This calls for new and improved processes for lithium production; one of them is electrodialysis (ED). Electrodialysis offers great potential in accessing lithium from brines in a more environmentally friendly way; furthermore, for the recovery of lithium from spent lithium-ion batteries (LIB), electrodialysis may become a vital technology. The following study focused on investigating the effect of varying brine compositions, different ED operation modes, and limiting factors on the use of ED for concentrating lithium-containing brine solutions. Synthetic lithium salt solutions (LiCl, LiOH) were concentrated using conventional ED in batch-wise operation. While the diluate solution was exchanged once a defined minimum concentration was reached, the concentrate solution was concentrated to the respective maximum. The experiments were conducted using a lab-scale ED-plant (BED1-3 from PCCell GmbH, Germany). The ion-exchange membranes used were PCSK and PCSA. The treated solutions varied in concentration and composition. Parameters such as current density, current efficiency, and energy requirements were evaluated. ED proved highly effective in the concentration of lithium salt solutions. Lithium chloride solutions were concentrated up to approximately 18-fold of the initial concentration. Current efficiencies and current densities depended on voltage, concentration, and the composition of the brine. Overall, the current efficiencies reached maximum values of around 70%. Furthermore, the experiments revealed a water transport of about 0.05 to 0.075% per gram of LiCl transferred from the diluate solution to the concentrate solution.
Porous polymer membranes substantially contribute to an acceleration of sustainability transformation based on the energy efficient separation of liquid and gaseous mixtures. This rapid shift toward sustainable industrial processes leads to an increased demand for specifically tailored membranes. In order to predict membrane performance factors like permeability, selectivity and durability, the membrane formation process by film casting and phase inversion needs to be understood further. In recent years, computational models of the membrane formation process have been studied intensely. Their high spatial and temporal resolution allows a detailed quantitative description of phase inversion phenomena. New experimental techniques complement this development, as they provide quantitative data, e.g., on compositional changes of the polymer solution during membrane formation as well as the kinetic progression of the phase separation process. This state-of-the-art review compiles computational and experimental approaches that characterize the phase inversion process. We discuss how this methodological pluralism is necessary for improving the tailoring of membrane parameters, but that it is unlikely to be the way to the ultimate goal of a complete description of the evolution of the membrane structure from the initial demixing to the final solidification. Alternatively, we formulate an approach that includes a database of standardized and harmonized membrane performance data based on previously publicized data, as well as the application of artificial neural networks as a new powerful tool to link membrane production parameters to membrane performance.
Agents with antifungal activity play a vital role as therapeutics in health care, as do fungicides in agriculture. Effectiveness, toxicological profile, and eco-friendliness are among the properties used to select suitable substances. Furthermore, a steady supply of new agents with different modes of action is required to counter the well-known potential of human and phyto-pathogenic fungi to develop resistance against established antifungals. Here, we use an in vitro growth assay to investigate the activity of the calcineurin inhibitor tacrolimus in combination with the commercial fungicides cyproconazole and hymexazol, as well as with two earlier reported novel {2-(3-R-1H-1,2,4-triazol-5-yl)phenyl}amines, against the fungi Aspergillus niger, Colletotrichum higginsianum, Fusarium oxysporum and the oomycete Phytophthora infestans, which are notoriously harmful in agriculture. When tacrolimus was added in a concentration range from 0.25 to 25 mg/L to the tested antifungals (at a fixed concentration of 25 or 50 mg/L), the inhibitory activities were distinctly enhanced. Molecular docking calculations revealed triazole derivative 5, (2-(3-adamantan-1-yl)-1H-1,2,4-triazol-5-yl)-4-chloroaniline), as a potent inhibitor of chitin deacetylases (CDA) of Aspergillus nidulans and A. niger (AnCDA and AngCDA, respectively), which was stronger than the previously reported polyoxorin D, J075-4187, and chitotriose. The results are discussed in the context of potential synergism and molecular mode of action.
Hydroxybenzene, commonly known as phenol, is one of the most important organic commodity chemicals. To produce phenol, the cumene process is the most used process worldwide. A crucial step in this process is the Hock rearrangement, which has a major impact on the overall cumene consumption rate and determines the safety level of the process. The most used catalyst for the cleavage of cumene hydroperoxide (CHP) is sulfuric acid. Besides its strong corrosive property, which increases plant investment costs, it also requires neutralization after the decomposition step to prevent side reactions. In this study, we show that high-temperature-treated Linde Type X (LTX) zeolites exhibit a high activity for the peroxide cleavage step. In addition, the structure–activity relationship responsible for this good performance in the reaction system of the HOCK rearrangement was investigated. XRPD analyses revealed the formation of a new phase after temperature treatment above 900 °C. The Si/Al ratio determined by EDX suggested the formation of extra-framework aluminum, which was confirmed by solid-state NMR analysis. The newly formed extra-framework aluminum was found to be responsible for the high catalytic activity. BET analyses showed that the surface area drops at higher calcination temperatures. This leads to a lower catalytic activity for most known reactions. However, for this study, no decrease in activity has been observed. The newfound material shows extraordinarily high activity as a catalyst in the HOCK cleavage and has the potential to be a heterogeneous alternative to sulfuric acid for this reaction.
In recent years, three sovereign catastrophe risk pools have developed worldwide, offering climate insurance against natural disasters in emerging and developing economies:
• Caribbean Catastrophe Risk Insurance Facility (CCRIF) in the Caribbean
• African Risk Capacity (ARC) in Africa
• Pacific Catastrophe Risk Insurance Company (PCRIC) in the Pacific region
These pools have emerged against the backdrop of limited fiscal room for manoeuvre in emerging and developing economies. Increases in tax revenues or capital allocations are scarcely possible in these economies. Moreover, debt on the capital market often ends in debt relief, and this can jeopardise refinancing. Ultimately, the only measure remaining is to provide donations and aid that can be made available by the G7 countries, the World Bank or the World Health Organization, among others.
Today, IT infrastructure represents the central nervous system of every company. Many of the activities of our daily lives are handled via the Internet. There is a lack of an adequately sustainable awareness of the cyber risks to which companies are exposed due to advanced digital networking. This is partly due to the fact that the danger of so-called ‘cyber attacks’ is only partially palpable to many, with attacks going unnoticed in some cases. As a result of major incidents, such as WannaCry and Petya in 2017, or Emotet in 2019, awareness of these risks should be keen, and yet vulnerability remains high due to the often insufficient protections against cyber crime.
The challenges facing the reinsurance industry remain considerable. For the reinsurance sector, 2022 was marked not only by the ongoing coronavirus pandemic and claims due to natural disasters but also by the war in Ukraine, the energy crisis and inflation.
The Cologne Research Centre for Reinsurance analyses the latest developments in the reinsurance market and, where appropriate, monitors these through research projects. In the process, the Research Centre for Reinsurance links its research activities with practices in the reinsurance sector. Hereby, and facilitated through organisation of the annual Cologne Reinsurance Symposium and the Annual Meeting of the Sponsoring Group Reinsurance [Förderkreis Rückversicherung], a bi-directional transfer of knowledge between theory and practice is pursued. Unfortunately the Cologne Reinsurance Symposium for 2022 had to be cancelled due to COVID-19.
The content of these two scientific events, as well as the completed research projects, are incorporated into scholarship and instruction at the Institute of Insurance Studies, rounding out practice-oriented training in the field of reinsurance.
There are eight researchers and four professors currently on the staff of the Cologne Research Centre for Reinsurance. Thereby, all material and personnel costs are fully financed by third-party funds provided by the Sponsoring Group Reinsurance. This funding helped facilitate the doctorate of Mr Frank Cremer, among other things.
At the 14th Annual Meeting of the Sponsoring Group Reinsurance held in 2021, the decision was taken to continue to provide financial support to the non-profit organisation ‘Hilfe für Guinea e.V.’ Through its annual donation to this project, the Cologne Research Centre for Reinsurance fulfils the criterion of ‘social commitment’ required of an official research focus. The donation will benefit the La Lumière Scolaire project. This project finances the construction and operation of schools for the children of disabled and homeless people in Guinea.
The Cologne Research Centre for Reinsurance is accredited as an official research focus of the Cologne University of Applied Sciences.
Due to its location at the south-west coast of Ireland County (Co.) Cork is frequently affected by post tropical cyclones (PTCs). There have been several records of these post hurricanes in the past with the last severe PTC being Hurricane Ophelia in 2017. It caused severe disruption in the whole country, especially in Co. Cork with several thousand people without water, power and mobile service for up to 10 days and thousands of uprooted trees which blocked roads. PTCs, like Ophelia, will become more frequent under climate change conditions due to warmer sea surface temperatures and decreased vertical wind shear. Hence, hurricanes can reach northern latitudes more easily and have a higher chance of making landfall in Co. Cork. This thesis assesses the risk perception towards natural hazards (NHs) and the perception of the risk communication of hurricane Ophelia by the citizens of Co. Cork and suggests improvements in communication based on the people’s perception. This was achieved by conducting a standardised survey to analyse the perception. The risk communication chain, its content and media involved were evaluated with interviews with professionals involved in risk management in Ireland. Improvement suggestions were extracted of the survey and the expert interviews as well and have been ranked by the participating experts according to their importance. The people of Co. Cork are not overly concerned about being affected by NHs. The three hazards they feel threatened by most, after Ophelia hit the country, are storms, river floodings and hurricanes. Before Ophelia made landfall, they only ranked hurricanes in the 8th place (out of 8). Ergo, after experiencing Ophelia people are much more aware of hurricane risk in Ireland. People were very satisfied with the information they received during Ophelia. The improvements they wished for are: 1) information on how to deal with and how to prepare for impacts of the storm, 2) the impacts that can be expected locally and 3) information where to go to in case of severe impact to property. These are mostly in line with the improvements the experts ranked as most important for Cork. Experts voted the suggestion to include information on behavioural advice into risk communication before the NH hits and advice on how to organise for impacts afterwards as their number one priority. Their second rank is to have education and training for the citizens in Cork. On third place they voted for a change to impact forecasting. Even there are no central buildings or shelters available in Co. Cork, this improvement suggestion was only voted on rank 13 by the experts (out of 14). Having a participatory approach in risk communication can overcome the discrepancies between the wishes of the population and the ones of the experts and would lead to a better understanding of all stakeholders involved in risk communication and can reduce vulnerability of the people in Co. Cork to the impacts of NHs. The implementation of these activities would be in line with best practice examples and would support the guidelines of the Irish Framework for Major Emergency Management.