500 Naturwissenschaften und Mathematik
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Diese Arbeit wertet Leistellendaten von zwei Landkreisen aus und untersucht dabei, welche Veränderung hinsichtlich der mittleren Anzahl und Dauer von Rettungsdiensteinsätzen im Zeitraum der COVID-19-Pandemie aufgeteilt nach Stunden- und Tageskategorien besteht. Anschließend werden die Veränderungen von Anzahl und Dauer beider Landkreise verglichen, um diese auf Unterschiede zu prüfen. Da in der aktuellen Literatur unzureichend dargelegt ist, wie Veränderungen des Einsatzanzahl oder -dauer im Rettungsdienst zwischen Kreisen sowie über die Tage und Tagesstunden verteilt sind, trägt diese Untersuchung dazu bei diese Forschungslücke zu schließen. Die statistische Auswertung der Leitstellendaten umfasst mehrere Schritte, sodass zuerst eine Aufbereitung durchgeführt wird, bevor die mittlere Einsatzanzahl und -dauer für vier Zeiträume sowie die prozentuale Veränderung zwischen einem Zeitraum vor und drei Zeiträumen während der Pandemie ermittelt werden. Im Anschluss wird die Veränderung mittels Kruskal-Wallis-Test beziehungsweise Varianzanalyse nach Welch auf Signifikanz überprüft. Abschließend erfolgt ein qualitativer Vergleich zwischen den Kreisen. Die Untersuchung zeigt, dass hinsichtlich Einsatzanzahl und -dauer zu allen drei Zeitraumen in der Pandemie Zu- und Abnahmen auftreten. Die Anzahl nimmt zum ersten Zeitraum in beiden Kreisen überwiegend ab, sowie zum vierten Zeitraum mehrheitlich zu, während zum zweiten Zeitraum im Lahn-Dill-Kreis eine häufigere Abnahme und im Main-Taunus-Kreis eine geringfügig überwiegende Zunahme vorliegt. Die Einsatzdauer unterliegt zum zweiten Zeitraum im Lahn-Dill-Kreis einer überwiegenden Zunahme und im Main-Taunus-Kreis einer überwiegenden Abnahme, während zum dritten sowie vierten Zeitraum in beiden Kreisen einer Steigerung stattfindet. Im Vergleich beider Gebietskörperschaften zeigen bei der Einsatzanzahl die Veränderungen zum zweiten und vierten Zeitraum und bei der Dauer die Veränderungen zum dritten und vierten Zeitraum mit der Mehrheit der Stundenkategorien Gemeinsamkeiten. Das Pandemiegeschehens sowie die nichtpharmazeutischen Interventionen sowie deren Folgen stellen Faktoren für die Veränderung von Einsatzanzahl und -dauer dar. Die geografische Lage sowie die lokale Ausgestaltung von Rettungsdienst und Krankentransport begründen, zusätzlich zu den oben genannten Aspekten, Unterschiede zwischen den Kreisen.
Due to the global phenomenon of climate change the region of Mara Siana is projected to increasingly face extreme weather events that particularly comprise prolonged droughts and
heavier rainfalls. To be able to adequately adapt to these changing circumstances and maintain their livelihoods communities need to build respective capacities. As the main objective, this research aims at determining landowners’ climate change adaptative capacity (CCAC) across different villages in Mara Siana. Accordingly, a semi-quantitative approach was carried out including qualitative interviews and the subsequent quantitative calculation of CCAC based on a multidimensional indicator set and a respective coding
system. In addition to predominantly positive results of socio-cultural characteristics and the quality of natural resources, this work reveals clear weaknesses and potential for improvement in the areas of income security and financial stability, the expansion and resilience of infrastructure, and the relationship between communities and local authorities. Moreover, differences in capacity results are not only identified between the investigated villages as well as between individual households but also systemic disadvantage in capacity building affecting female landowners and community members can be indicated from the obtained interview data. Therefore, this research gives concrete recommendations for the implementation and verification of suitable adaptive measures that are particularly tailored for the improvement of low-performance indicators while following a gendertransformative approach and thus hold the potential to increase CCAC in the long-term.
Current changes in environmental legislation and customer demands set an urge for the development of more sustainable surfactants. Thus, the objective of this work was the development of novel environmentally friendly amino acid surfactants. Combining Diels–Alder cyclization of myrcene with maleic or citraconic anhydride followed by ring opening with amino acids enabled a synthesis route with a principal 100% atom economy. Variation of amino acids resulted in a large structural variety of anionic and amphoteric surfactants. Lysine gave access to either a mono-acylated product bearing a cationic side chain or a bi-acylated gemini surfactant. First, anhydride precursors were synthesized in yields of >90% in a Diels–Alder reaction under microwave radiation and subsequent amino acid coupling in aqueous environment gave fully bio-based surfactants in good yields and purity. Physicochemical characterization showed an enhanced decrease in surface tension upon addition of amino acids to the myrcene–anhydride backbone, resulting in a minimal value of 31 mN·m−1 for gemini–lysine. Foamabilitiy and foam stability were significantly increased at skin-friendly pH 5.5 by incorporation of amino acids. The carboxylic groups of surfactants with arginine were esterified with ethanol to access cationic compounds. Comparative analysis revealed moderate antimicrobial effects against yeast, Gram-positive bacteria, and Gram-negative bacteria.
The teaching of civil engineering consists of different didactic approaches, such as lectures, group work or research-based teaching, depending on the respective courses. Currently, the metaverse is gaining importance in teaching and offers the possibility of a new teaching approach for civil engineering and especially for the teaching of courses from the areas of “Digital Design and Construction”. Although the advantages of teaching in the metaverse, such as location and time independence or a higher learning outcome, are mentioned in the literature, there are also challenges that must be considered when teaching in the metaverse. Against this background, this paper examines the implications of using the metaverse as a teaching tool in teaching “Digital Design and Construction”. The impact of teaching BIM in the metaverse is evaluated by (1) a literature review and workshops to evaluate use cases and demands for extended reality (XR) and the metaverse, (2) integrating XR and the metaverse in the courses and valuation by quantitative evaluations and (3) analyzing student papers of the courses and outcomes of a World Café. Due to these steps, this paper presents a novel approach by reflecting the students’ perspective. Furthermore, this paper presents a validated approach for integrating BIM and the metaverse in teaching.
This study explores the potential of robust, strongly basic type I ion exchange resins—specifically, Amberlyst® A26 OH and Lewatit® K 6465—as catalysts for the aldol condensation of citral and acetone, yielding pseudoionone. Emphasis is placed on their long-term stability and commendable performance in continuous operational settings. The aldol reaction, which traditionally is carried out using aqueous sodium hydroxide as the catalyst, holds the potential for enhanced sustainability and reduced waste production through the use of basic ion exchange resins in heterogeneous catalysis. Density Functional Theory (DFT) calculations are employed to investigate catalyst deactivation mechanisms. The result of these calculations indicates that the active sites of Amberlyst® A26 OH are cleaved more easily than the active sites of Lewatit® K 6465. However, the experimental data show a gradual decline in catalytic activity for both resins. Batch experiments reveal Amberlyst® A26 OH’s active sites diminishing, while Lewatit® K 6465 maintains relative consistency. This points to distinct deactivation processes for each catalyst. The constant count of basic sites in Lewatit® K 6465 during the reaction suggests additional factors due to its unique polymer structure. This intriguing observation also highlights an exceptional temperature stability for Lewatit® K 6465 compared to Amberlyst® A26 OH, effectively surmounting one of the prominent challenges associated with the utilization of ion exchange resins in catalytic applications.
A novel approach to manufacture components with integrated conductor paths involves embedding and sintering an isotropic conductive adhesive (ICA) during fused filament fabrication (FFF). However, the molten plastic is deposited directly onto the adhesive path which causes an inhomogeneous displacement of the uncured ICA. This paper presents a 3D printing strategy to achieve a homogeneous cross-section of the conductor path. The approach involves embedding the ICA into a printed groove and sealing it with a wide extruded plastic strand. Three parameter studies are conducted to obtain a consistent cavity for uniform formation of the ICA path. Specimens made of polylactic acid (PLA) with embedded ICA paths are printed and evaluated. The optimal parameters include a groove printed with a layer height of 0.1 mm, depth of 0.4 mm, and sealed with a PLA strand of 700 µm diameter. This resulted in a conductor path with a homogeneous cross-section, measuring 660 µm ± 22 µm in width (relative standard deviation: 3.3%) and a cross-sectional area of 0.108 mm2 ± 0.008 mm2 (relative standard deviation 7.2%). This is the first study to demonstrate the successful implementation of a printing strategy for embedding conductive traces with a homogeneous cross-sectional area in FFF 3D printing.
The internal armed conflict in Colombia has been closely linked to the illegal exploitation of natural resources and the appropriation of territories, including the planting of illicit coca crops. This activity has led to deforestation and the degradation of natural ecosystems, aggravating the problems associated with violence and drug trafficking. Regions with little state presence, such as Catatumbo, were particularly affected.
Following the signing of the peace agreement with the Revolutionary Armed Forces of Colombia (FARC) in 2016, a post-agreement scenario emerged that highlighted the need to address complex socio-environmental conflicts in affected regions. This research aims to identify the potential of environmental governance to contribute to peacebuilding and the reduction of deforestation associated with illicit coca cultivation.
A qualitative methodological approach was used in this study, which seeks to integrate research methods and techniques such as: documentary review, participant observation, semi-structured and in-depth interviews, and mapping of the current reality through the Theory U 3D mapping tool.
The results include the socio-environmental context of the territory of analysis, describing the origins of the conflict of deforestation for illicit crops, where the growing dynamics of transformation of the sowing of illicit crops are related, as well as the dynamics of deforestation in the territory of analysis. Tthe identification and analysis of the most relevant actors that have historically participated in the processes of deforestation for illicit crops, their characterization according to the relations of power, interest and legitimisation legitimization. The forms of participation and conflict resolution in the management of natural resources.
Considering as a contextual axis two important processes at a socio-political level in Colombia and the territory under analysis, which correspond to the consolidation of the Comprehensive Rural Reform after the peace agreement and the post-agreement context. Several intervention proposals were proposed from the perspective of environmental governance related to the reconstruction of the social fabric, the reconversion of productive systems, and the resignification of new dynamics of natural resource management. In this sense, the potential of environmental governance is discussed as a useful framework for establishing new relationships based on horizontality in which the actors possess sovereignty over the territory, participation and representativeness in the management of natural resources.
Key words: Deforestation, illicit coca crops, environmental governance, forest management, peacebuilding.
Mangrove forests have been studied broadly in the recent three decades for their outstanding ability to sequester carbon in the beneath soil and other beneficial ecosystem services. Endeavors to conserve and regenerate mangrove cover are still increasing worldwide as a mechanism to include them in NDCs and carbon markets. Therefore, decision-makers in the private and public sectors require identify possible areas for conservation and restoration prior to blue carbon project investment. Thus, an integral assessment of potential mangrove carbon reservoirs in a landscape scale, considering environmental and socioeconomic factors was performed. This study was aimed to determine areas with the highest blue carbon sequestration potential in the Gulf of Guayaquil through the construction of a Blue Carbon Potential Index (BCPI) based on Spatial Multicriteria Analysis (SMCA). A narrative integrative literature review was employed to select indicators of mangrove carbon sequestration gains and losses. These indicators were pondered following the Analytical Hierarchy Process (AHP) with the judgments of two experts and reclassified in four potential categories based on their thresholds. Since no consensus was achieved in the indicator importance hierarchization, a comparative of equal weighting method and AHP weighting was implemented. The linear combination rule was used to integrate these factors into a unique-scaled index supported by a geographic Information System (GIS). The results showed that 15.82% and 16.21% of the study area belonged to high and moderate potential of blue carbon sequestration respectively. Moreover, no significant differences were found between the two weighting methods applied. The BCPI provides a comprehensive understanding of spatial distribution of blue carbon potential reservoirs and grants a quantification of this potential to prioritize conservation and restoration areas.
Aim: European cities are facing heighten hydrological risks as a result of climate change at the same time as ecological degradation has reduced the environmental capacity to absorb and regulate such fluctuations. Climate forecasts predict more intense convective rainfall and winter flood events in the Wupper Basin in Germany, against a background trend of reduced mean rainfall during the summer months. On 14 July 2021 intense convective rainfall fell at points across Western Germany and led to flash floods in the Wupper Basin, many sites were inundated and the Wupper and Dhünn rivers rose to new record highs. Green-blue infrastructure offers strategies to reduce the impacts of hazards at the same time as providing a range of co-benefits. A study was undertaken to find which green-blue interventions will be most effective at reducing the impacts of hydrometeorological hazards for a study area in the west of the Wupper basin. Furthermore, as landscape features are highly influential in hydrology, the study sought to establish which sites within the landscape can provide maximum results from green-blue interventions, with a minimum of change to current land uses.
Region: Europe, peri-urban and rural, undulating, low mountainous landscapes
Methods: Literature findings on observed and projected climate data are summarised and long-term rainfall data from the study area is analysed to confirm rainfall trends. A state-of-the-art review is conducted and summarised to form a toolbox of potential interventions. The most recent hazardous hydrometeorological event is analysed to inform the locational priorities of potential interventions. Landscape features that have the most influence on basin hydrology are identified from the literature. These sites are paired with green-blue interventions that are shown to have the highest potential impact on interception, infiltration, runoff and flooding. A series of spatial analyses are carried out to produce maps detailing location and intervention with high potential to reduce the impact of hydrometeorological hazards in the study area. All of the evidence gathered from the literature analysis is combined in an implementation guide for green-blue interventions in the Wupper Basin.
Results: The hazards caused by the hydrometeorological extremes of flooding and drought are addressed or minimised through the green-blue interventions that increase interception and infiltration and reduce runoff and flooding. Priority locations are identified as the riparian zone with slope ≤15%, hilltop, lower slope and toe slope, all locations with a slope ≥30% and areas with a high topographic wetness index (TWI). A series of spatial analyses were carried out and suggestions made including potential locations for retention or detention areas and ponds, sites for revegetation and potential locations for implementation of shelterbelts/hedgerows, buffer strips, conservation tillage or strip tillage, reduced mowing intensity or frequency and biochar additions. An implementation guide is created that provides a summary of the highest potential green-blue interventions and landscape locations, and a description of the mechanisms involved in addressing the hydrometeorological hazards.
Keywords: Green-blue interventions, hydrometeorological hazard reduction, Wupper Basin hydrology
In the last decade, the utilization of waste by-product apple pomace has been extensively researched (due to its difficult disposal) and currently finds beneficial usage in various industries; as substrate for microbial growth or recovery of pectin, xyloglucan and polyphenols. In this research apple juice was produced at pilot scale. Furthermore, apple pomace was employed as substrate for the production of pectin, biofuel (pellets) and concentrated apple pomace extract. Extensive mass and heat balances were conducted to evaluate the feasibility of this approach on industrial scale. The produced pellets had very similar characteristics to wood pellets (net calorific value of 20.3 MJ/kg). Dried apple pomace contained 11.9% of pectin. Fed-batch cultivation of baker´s yeast with apple pomace extract demonstrated a potential for partial substitution of molasses in industrial bioprocesses. This concept shows how a zero discharge biorefinery process converts waste from apple juice production into three valuable products enabling connections between different industries.