500 Naturwissenschaften und Mathematik
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Diese Arbeit wertet Leistellendaten von zwei Landkreisen aus und untersucht dabei, welche Veränderung hinsichtlich der mittleren Anzahl und Dauer von Rettungsdiensteinsätzen im Zeitraum der COVID-19-Pandemie aufgeteilt nach Stunden- und Tageskategorien besteht. Anschließend werden die Veränderungen von Anzahl und Dauer beider Landkreise verglichen, um diese auf Unterschiede zu prüfen. Da in der aktuellen Literatur unzureichend dargelegt ist, wie Veränderungen des Einsatzanzahl oder -dauer im Rettungsdienst zwischen Kreisen sowie über die Tage und Tagesstunden verteilt sind, trägt diese Untersuchung dazu bei diese Forschungslücke zu schließen. Die statistische Auswertung der Leitstellendaten umfasst mehrere Schritte, sodass zuerst eine Aufbereitung durchgeführt wird, bevor die mittlere Einsatzanzahl und -dauer für vier Zeiträume sowie die prozentuale Veränderung zwischen einem Zeitraum vor und drei Zeiträumen während der Pandemie ermittelt werden. Im Anschluss wird die Veränderung mittels Kruskal-Wallis-Test beziehungsweise Varianzanalyse nach Welch auf Signifikanz überprüft. Abschließend erfolgt ein qualitativer Vergleich zwischen den Kreisen. Die Untersuchung zeigt, dass hinsichtlich Einsatzanzahl und -dauer zu allen drei Zeitraumen in der Pandemie Zu- und Abnahmen auftreten. Die Anzahl nimmt zum ersten Zeitraum in beiden Kreisen überwiegend ab, sowie zum vierten Zeitraum mehrheitlich zu, während zum zweiten Zeitraum im Lahn-Dill-Kreis eine häufigere Abnahme und im Main-Taunus-Kreis eine geringfügig überwiegende Zunahme vorliegt. Die Einsatzdauer unterliegt zum zweiten Zeitraum im Lahn-Dill-Kreis einer überwiegenden Zunahme und im Main-Taunus-Kreis einer überwiegenden Abnahme, während zum dritten sowie vierten Zeitraum in beiden Kreisen einer Steigerung stattfindet. Im Vergleich beider Gebietskörperschaften zeigen bei der Einsatzanzahl die Veränderungen zum zweiten und vierten Zeitraum und bei der Dauer die Veränderungen zum dritten und vierten Zeitraum mit der Mehrheit der Stundenkategorien Gemeinsamkeiten. Das Pandemiegeschehens sowie die nichtpharmazeutischen Interventionen sowie deren Folgen stellen Faktoren für die Veränderung von Einsatzanzahl und -dauer dar. Die geografische Lage sowie die lokale Ausgestaltung von Rettungsdienst und Krankentransport begründen, zusätzlich zu den oben genannten Aspekten, Unterschiede zwischen den Kreisen.
Due to the global phenomenon of climate change the region of Mara Siana is projected to increasingly face extreme weather events that particularly comprise prolonged droughts and
heavier rainfalls. To be able to adequately adapt to these changing circumstances and maintain their livelihoods communities need to build respective capacities. As the main objective, this research aims at determining landowners’ climate change adaptative capacity (CCAC) across different villages in Mara Siana. Accordingly, a semi-quantitative approach was carried out including qualitative interviews and the subsequent quantitative calculation of CCAC based on a multidimensional indicator set and a respective coding
system. In addition to predominantly positive results of socio-cultural characteristics and the quality of natural resources, this work reveals clear weaknesses and potential for improvement in the areas of income security and financial stability, the expansion and resilience of infrastructure, and the relationship between communities and local authorities. Moreover, differences in capacity results are not only identified between the investigated villages as well as between individual households but also systemic disadvantage in capacity building affecting female landowners and community members can be indicated from the obtained interview data. Therefore, this research gives concrete recommendations for the implementation and verification of suitable adaptive measures that are particularly tailored for the improvement of low-performance indicators while following a gendertransformative approach and thus hold the potential to increase CCAC in the long-term.
Current changes in environmental legislation and customer demands set an urge for the development of more sustainable surfactants. Thus, the objective of this work was the development of novel environmentally friendly amino acid surfactants. Combining Diels–Alder cyclization of myrcene with maleic or citraconic anhydride followed by ring opening with amino acids enabled a synthesis route with a principal 100% atom economy. Variation of amino acids resulted in a large structural variety of anionic and amphoteric surfactants. Lysine gave access to either a mono-acylated product bearing a cationic side chain or a bi-acylated gemini surfactant. First, anhydride precursors were synthesized in yields of >90% in a Diels–Alder reaction under microwave radiation and subsequent amino acid coupling in aqueous environment gave fully bio-based surfactants in good yields and purity. Physicochemical characterization showed an enhanced decrease in surface tension upon addition of amino acids to the myrcene–anhydride backbone, resulting in a minimal value of 31 mN·m−1 for gemini–lysine. Foamabilitiy and foam stability were significantly increased at skin-friendly pH 5.5 by incorporation of amino acids. The carboxylic groups of surfactants with arginine were esterified with ethanol to access cationic compounds. Comparative analysis revealed moderate antimicrobial effects against yeast, Gram-positive bacteria, and Gram-negative bacteria.
The teaching of civil engineering consists of different didactic approaches, such as lectures, group work or research-based teaching, depending on the respective courses. Currently, the metaverse is gaining importance in teaching and offers the possibility of a new teaching approach for civil engineering and especially for the teaching of courses from the areas of “Digital Design and Construction”. Although the advantages of teaching in the metaverse, such as location and time independence or a higher learning outcome, are mentioned in the literature, there are also challenges that must be considered when teaching in the metaverse. Against this background, this paper examines the implications of using the metaverse as a teaching tool in teaching “Digital Design and Construction”. The impact of teaching BIM in the metaverse is evaluated by (1) a literature review and workshops to evaluate use cases and demands for extended reality (XR) and the metaverse, (2) integrating XR and the metaverse in the courses and valuation by quantitative evaluations and (3) analyzing student papers of the courses and outcomes of a World Café. Due to these steps, this paper presents a novel approach by reflecting the students’ perspective. Furthermore, this paper presents a validated approach for integrating BIM and the metaverse in teaching.
This study explores the potential of robust, strongly basic type I ion exchange resins—specifically, Amberlyst® A26 OH and Lewatit® K 6465—as catalysts for the aldol condensation of citral and acetone, yielding pseudoionone. Emphasis is placed on their long-term stability and commendable performance in continuous operational settings. The aldol reaction, which traditionally is carried out using aqueous sodium hydroxide as the catalyst, holds the potential for enhanced sustainability and reduced waste production through the use of basic ion exchange resins in heterogeneous catalysis. Density Functional Theory (DFT) calculations are employed to investigate catalyst deactivation mechanisms. The result of these calculations indicates that the active sites of Amberlyst® A26 OH are cleaved more easily than the active sites of Lewatit® K 6465. However, the experimental data show a gradual decline in catalytic activity for both resins. Batch experiments reveal Amberlyst® A26 OH’s active sites diminishing, while Lewatit® K 6465 maintains relative consistency. This points to distinct deactivation processes for each catalyst. The constant count of basic sites in Lewatit® K 6465 during the reaction suggests additional factors due to its unique polymer structure. This intriguing observation also highlights an exceptional temperature stability for Lewatit® K 6465 compared to Amberlyst® A26 OH, effectively surmounting one of the prominent challenges associated with the utilization of ion exchange resins in catalytic applications.
A novel approach to manufacture components with integrated conductor paths involves embedding and sintering an isotropic conductive adhesive (ICA) during fused filament fabrication (FFF). However, the molten plastic is deposited directly onto the adhesive path which causes an inhomogeneous displacement of the uncured ICA. This paper presents a 3D printing strategy to achieve a homogeneous cross-section of the conductor path. The approach involves embedding the ICA into a printed groove and sealing it with a wide extruded plastic strand. Three parameter studies are conducted to obtain a consistent cavity for uniform formation of the ICA path. Specimens made of polylactic acid (PLA) with embedded ICA paths are printed and evaluated. The optimal parameters include a groove printed with a layer height of 0.1 mm, depth of 0.4 mm, and sealed with a PLA strand of 700 µm diameter. This resulted in a conductor path with a homogeneous cross-section, measuring 660 µm ± 22 µm in width (relative standard deviation: 3.3%) and a cross-sectional area of 0.108 mm2 ± 0.008 mm2 (relative standard deviation 7.2%). This is the first study to demonstrate the successful implementation of a printing strategy for embedding conductive traces with a homogeneous cross-sectional area in FFF 3D printing.
The internal armed conflict in Colombia has been closely linked to the illegal exploitation of natural resources and the appropriation of territories, including the planting of illicit coca crops. This activity has led to deforestation and the degradation of natural ecosystems, aggravating the problems associated with violence and drug trafficking. Regions with little state presence, such as Catatumbo, were particularly affected.
Following the signing of the peace agreement with the Revolutionary Armed Forces of Colombia (FARC) in 2016, a post-agreement scenario emerged that highlighted the need to address complex socio-environmental conflicts in affected regions. This research aims to identify the potential of environmental governance to contribute to peacebuilding and the reduction of deforestation associated with illicit coca cultivation.
A qualitative methodological approach was used in this study, which seeks to integrate research methods and techniques such as: documentary review, participant observation, semi-structured and in-depth interviews, and mapping of the current reality through the Theory U 3D mapping tool.
The results include the socio-environmental context of the territory of analysis, describing the origins of the conflict of deforestation for illicit crops, where the growing dynamics of transformation of the sowing of illicit crops are related, as well as the dynamics of deforestation in the territory of analysis. Tthe identification and analysis of the most relevant actors that have historically participated in the processes of deforestation for illicit crops, their characterization according to the relations of power, interest and legitimisation legitimization. The forms of participation and conflict resolution in the management of natural resources.
Considering as a contextual axis two important processes at a socio-political level in Colombia and the territory under analysis, which correspond to the consolidation of the Comprehensive Rural Reform after the peace agreement and the post-agreement context. Several intervention proposals were proposed from the perspective of environmental governance related to the reconstruction of the social fabric, the reconversion of productive systems, and the resignification of new dynamics of natural resource management. In this sense, the potential of environmental governance is discussed as a useful framework for establishing new relationships based on horizontality in which the actors possess sovereignty over the territory, participation and representativeness in the management of natural resources.
Key words: Deforestation, illicit coca crops, environmental governance, forest management, peacebuilding.
Mangrove forests have been studied broadly in the recent three decades for their outstanding ability to sequester carbon in the beneath soil and other beneficial ecosystem services. Endeavors to conserve and regenerate mangrove cover are still increasing worldwide as a mechanism to include them in NDCs and carbon markets. Therefore, decision-makers in the private and public sectors require identify possible areas for conservation and restoration prior to blue carbon project investment. Thus, an integral assessment of potential mangrove carbon reservoirs in a landscape scale, considering environmental and socioeconomic factors was performed. This study was aimed to determine areas with the highest blue carbon sequestration potential in the Gulf of Guayaquil through the construction of a Blue Carbon Potential Index (BCPI) based on Spatial Multicriteria Analysis (SMCA). A narrative integrative literature review was employed to select indicators of mangrove carbon sequestration gains and losses. These indicators were pondered following the Analytical Hierarchy Process (AHP) with the judgments of two experts and reclassified in four potential categories based on their thresholds. Since no consensus was achieved in the indicator importance hierarchization, a comparative of equal weighting method and AHP weighting was implemented. The linear combination rule was used to integrate these factors into a unique-scaled index supported by a geographic Information System (GIS). The results showed that 15.82% and 16.21% of the study area belonged to high and moderate potential of blue carbon sequestration respectively. Moreover, no significant differences were found between the two weighting methods applied. The BCPI provides a comprehensive understanding of spatial distribution of blue carbon potential reservoirs and grants a quantification of this potential to prioritize conservation and restoration areas.
Aim: European cities are facing heighten hydrological risks as a result of climate change at the same time as ecological degradation has reduced the environmental capacity to absorb and regulate such fluctuations. Climate forecasts predict more intense convective rainfall and winter flood events in the Wupper Basin in Germany, against a background trend of reduced mean rainfall during the summer months. On 14 July 2021 intense convective rainfall fell at points across Western Germany and led to flash floods in the Wupper Basin, many sites were inundated and the Wupper and Dhünn rivers rose to new record highs. Green-blue infrastructure offers strategies to reduce the impacts of hazards at the same time as providing a range of co-benefits. A study was undertaken to find which green-blue interventions will be most effective at reducing the impacts of hydrometeorological hazards for a study area in the west of the Wupper basin. Furthermore, as landscape features are highly influential in hydrology, the study sought to establish which sites within the landscape can provide maximum results from green-blue interventions, with a minimum of change to current land uses.
Region: Europe, peri-urban and rural, undulating, low mountainous landscapes
Methods: Literature findings on observed and projected climate data are summarised and long-term rainfall data from the study area is analysed to confirm rainfall trends. A state-of-the-art review is conducted and summarised to form a toolbox of potential interventions. The most recent hazardous hydrometeorological event is analysed to inform the locational priorities of potential interventions. Landscape features that have the most influence on basin hydrology are identified from the literature. These sites are paired with green-blue interventions that are shown to have the highest potential impact on interception, infiltration, runoff and flooding. A series of spatial analyses are carried out to produce maps detailing location and intervention with high potential to reduce the impact of hydrometeorological hazards in the study area. All of the evidence gathered from the literature analysis is combined in an implementation guide for green-blue interventions in the Wupper Basin.
Results: The hazards caused by the hydrometeorological extremes of flooding and drought are addressed or minimised through the green-blue interventions that increase interception and infiltration and reduce runoff and flooding. Priority locations are identified as the riparian zone with slope ≤15%, hilltop, lower slope and toe slope, all locations with a slope ≥30% and areas with a high topographic wetness index (TWI). A series of spatial analyses were carried out and suggestions made including potential locations for retention or detention areas and ponds, sites for revegetation and potential locations for implementation of shelterbelts/hedgerows, buffer strips, conservation tillage or strip tillage, reduced mowing intensity or frequency and biochar additions. An implementation guide is created that provides a summary of the highest potential green-blue interventions and landscape locations, and a description of the mechanisms involved in addressing the hydrometeorological hazards.
Keywords: Green-blue interventions, hydrometeorological hazard reduction, Wupper Basin hydrology
In the last decade, the utilization of waste by-product apple pomace has been extensively researched (due to its difficult disposal) and currently finds beneficial usage in various industries; as substrate for microbial growth or recovery of pectin, xyloglucan and polyphenols. In this research apple juice was produced at pilot scale. Furthermore, apple pomace was employed as substrate for the production of pectin, biofuel (pellets) and concentrated apple pomace extract. Extensive mass and heat balances were conducted to evaluate the feasibility of this approach on industrial scale. The produced pellets had very similar characteristics to wood pellets (net calorific value of 20.3 MJ/kg). Dried apple pomace contained 11.9% of pectin. Fed-batch cultivation of baker´s yeast with apple pomace extract demonstrated a potential for partial substitution of molasses in industrial bioprocesses. This concept shows how a zero discharge biorefinery process converts waste from apple juice production into three valuable products enabling connections between different industries.
The paper presents results of the modelling of heat transfer at film boiling of a liquid in a porous medium on a vertical heated wall bordering with the porous medium. Such processes are observed at cooling of high-temperature surfaces of heat pipes, microstructural radiators etc. Heating conditions at the wall were the constant wall temperature or heat flux. The outer boundary of the vapor film was in contact with moving or stationary liquid inside the porous medium. An analytical solution was obtained for the problem of fluid flow and heat transfer using the porous medium model in the Darcy–Brinkman and Darcy–Brinkman–Forchheimer approximation. It was shown that heat transfer at film boiling in a porous medium was less intensive than in the absence of a porous medium (free fluid flow) and further decreased with the decreasing permeability of the porous medium. Significant differences were observed in frames of both models: 20% for small Darcy numbers at Da < 2 for the Darcy–Brinkman model, and 80% for the Darcy–Brinkman–Forchheimer model. In the Darcy–Brinkman model, depending on the interaction conditions at the vapor–liquid interface (no mechanical interaction or stationary fluid), a sharp decrease in heat transfer was observed for the Darcy numbers lower than five. The analytical predictions of heat transfer coefficients qualitatively agreed with the data of Cheng and Verma (Int J Heat Mass Transf 24:1151–1160, 1981) though demonstrated lower values of heat transfer coefficients for the conditions of the constant wall temperature and constant wall heat flux.
The paper focused on an analytical analysis of the main features of heat transfer in incompressible steady-state flow in a microconfusor with account for the second-order slip boundary conditions. The second-order boundary conditions serve as a closure of a system of the continuity, transport, and energy differential equations. As a result, novel solutions were obtained for the velocity and temperature profiles, as well as for the friction coefficient and the Nusselt number. These solutions demonstrated that an increase in the Knudsen number leads to a decrease in the Nusselt number. It was shown that the account for the second-order terms in the boundary conditions noticeably affects the fluid flow characteristics and does not influence on the heat transfer characteristics. It was also revealed that flow slippage effects on heat transfer weaken with an increase in the Prandtl number.
To date, the establishment of high-titer stable viral packaging cells (VPCs) at large scale for gene therapeutic applications is very time- and cost-intensive. Here we report the establishment of three human suspension 293-F-derived ecotropic MLV-based VPCs. The classic stable transfection of an EGFP-expressing transfer vector resulted in a polyclonal VPC pool that facilitated cultivation in shake flasks of 100 mL volumes and yielded high functional titers of more than 1 × 106 transducing units/mL (TU/mL). When the transfer vector was flanked by transposon terminal inverted repeats (TIRs) and upon co-transfection of a plasmid encoding for the transposase, productivities could be slightly elevated to more than 3 × 106 TU/mL. In contrast and using mRNA encoding for the transposase, as a proof of concept, productivities were drastically improved by more than ten-fold exceeding 5 × 107 TU/mL. In addition, these VPC pools were generated within only 3 weeks. The production volume was successfully scaled up to 500 mL employing a stirred-tank bioreactor (STR). We anticipate that the stable transposition of transfer vectors employing transposase transcripts will be of utility for the future establishment of high-yield VPCs producing pseudotype vector particles with a broader host tropism on a large scale.
Stable recombinant mammalian cells are of growing importance in pharmaceutical biotechnology production scenarios for biologics such as monoclonal antibodies, growth and blood factors, cytokines and subunit vaccines. However, the establishment of recombinant producer cells using classical stable transfection of plasmid DNA is hampered by low stable gene transfer efficiencies. Consequently, subsequent selection of transgenic cells and the screening of clonal cell populations are time- and thus cost-intensive. To overcome these limitations, expression cassettes were embedded into transposon-derived donor vectors. Upon the co-transfection with transposase-encoding constructs, elevated vector copy numbers stably integrated into the genomes of the host cells are readily achieved facilitating under stringent selection pressure the establishment of cell pools characterized by sustained and high-yield recombinant protein production. Here, we discuss some aspects of transposon vector technologies, which render these vectors promising candidates for their further utilization in the production of biologics.
Reducing the carbon emissions from hotels on non-interconnected islands (NII) is essential in the context of a low carbon future for the Mediterranean region. Maritime tourism is the major source of income for Greece and many other countries in the region, as well as hot-temperate and tropical regions worldwide. Like many NIIs, Rhodes attracts a high influx of tourists every summer, doubling the island’s energy demand and, given the high proportion of fossil fuels in the Rhodian energy supply, increasing carbon emissions. Using the theoretical framework ‘FINE’, this paper presents the optimisation of a medium-sized hotel’s energy system with the aim of reducing both cost and carbon emissions. By introducing a Photovoltaic (PV) net metering system, it was found that the carbon emissions associated with an NII hotel’s energy system could be reduced by 31% at an optimised cost. It is suggested that large-scale deployment of PV or alternative renewable energy sources (RES) in NII hotels could significantly reduce carbon emissions associated with the accommodation sector in Greece and help mitigate climate change.
Steer-by-wire systems represent a key technology for highly automated and autonomous driving. In this context, robust steering control is a fundamental precondition for automated vehicle lateral control. However, there is a need for improvement due to degrees of freedom, signal delays, and nonlinear characteristics of the plant which are unconsidered in the design models for the design of current steering controls. To be able to design an extremely robust steering control, suitable optimal models of a steer-by-wire system are required. Therefore, this paper presents an innovative nonlinear detail model of a steer-by-wire system. The detail model represents all characteristics of a real steer-by-wire system. In the context of a dominance analysis of the detail model, all dominant characteristics of a steer-by-wire system, including parameter dependencies, are identified. Through model reduction, a reduced model of the steer-by-wire system is then developed that can be used for a subsequent robust control design. Furthermore, this paper compares the steer-by-wire system with a conventional electromechanical power steering and shows similarities as well as differences.
Positive Impact of Red Soil on Albedo and the Annual Yield of Bifacial Photovoltaic Systems in Ghana
(2023)
The annual yield of bifacial photovoltaic systems is highly dependent on the albedo of the underlying soil. There are currently no published data about the albedo of red soil in western Africa. In this study, the impact of the albedo of red soil in Ghana on the energy yield of bifacial photovoltaic systems is analysed. A bifacial photovoltaic simulation model is created by combining the optical view factor matrix with an electrical output simulation. For an exact simulation, the albedo of red soil at three different locations in Ghana is measured for the first time. The average albedo of every red soil is clearly determined, as well as the measurement span including instrumentation uncertainty; values between 0.175 and 0.335 were measured. Considering these data, a state-of-the-art bifacial photovoltaic system with an average of 19.8% efficient modules in northern Ghana can achieve an annual energy yield of 508.8 kWh/m2 and a bifacial gain of up to 18.3% in comparison with monofacial photovoltaic panels. To summarise, red soil in two out of three locations in Ghana shows higher albedo values than most natural ground surfaces and therefore positively impacts the annual yield of bifacial photovoltaic systems.
To date, the establishment of high-titer stable viral packaging cells (VPCs) at large scale for gene therapeutic applications is very time- and cost-intensive. Here we report the establishment of three human suspension 293-F-derived ecotropic MLV-based VPCs. The classic stable transfection of an EGFP-expressing transfer vector resulted in a polyclonal VPC pool that facilitated cultivation in shake flasks of 100 mL volumes and yielded high functional titers of more than 1 × 106 transducing units/mL (TU/mL). When the transfer vector was flanked by transposon terminal inverted repeats (TIRs) and upon co-transfection of a plasmid encoding for the transposase, productivities could be slightly elevated to more than 3 × 106 TU/mL. In contrast and using mRNA encoding for the transposase, as a proof of concept, productivities were drastically improved by more than ten-fold exceeding 5 × 107 TU/mL. In addition, these VPC pools were generated within only 3 weeks. The production volume was successfully scaled up to 500 mL employing a stirred-tank bioreactor (STR). We anticipate that the stable transposition of transfer vectors employing transposase transcripts will be of utility for the future establishment of high-yield VPCs producing pseudotype vector particles with a broader host tropism on a large scale.
Austria is committed to the net-zero climate goal along with the European Union. This requires all sectors to be decarbonized. Hereby, hydrogen plays a vital role as stated in the national hydrogen strategy. A report commissioned by the Austrian government predicts a minimum hydrogen demand of 16 TWh per year in Austria in 2040. Besides hydrogen imports, domestic production can ensure supply. Hence, this study analyses the levelized cost of hydrogen for an off-grid production plant including a proton exchange membrane electrolyzer, wind power and solar photovoltaics in Austria. In the first step, the capacity factors of the renewable electricity sources are determined by conducting a geographic information system analysis. Secondly, the levelized cost of electricity for wind power and solarphotovoltaics plants in Austria is calculated. Thirdly, the most cost-efficient portfolio of wind power and solar photovoltaics plants is determined using electricity generation profiles with a 10-min granularity. The modelled system variants differ among location, capacity factors of the renewable electricity sources and the full load hours of the electrolyzer. Finally, selected variables are tested for their sensitivities. With the applied model, the hydrogen production cost for decentralized production plants can be calculated for any specific location. The levelized cost of hydrogen estimates range from 3.08 EUR/kg to 13.12 EUR/kg of hydrogen, whereas it was found that the costs are most sensitive to the capacity factors of the renewable electricity sources and the full load hours of the electrolyzer. The novelty of the paper stems from the model applied that calculates the levelized cost of renewable hydrogen in an off-grid hydrogen production system. The model finds a cost-efficient portfolio of directly coupled wind power and solar photovoltaics systems for 80 different variants in an Austria-specific context.
One-step preparation of bilayered films from kraft lignin and cellulose acetate to mimic tree bark
(2020)
This contribution presents the development of a dry-cast method for the one-step preparation of bio-based films from wood polymers that mimic the bilayered structure of tree bark, the natural protective layer of the tree. In a simplified view, natural bark can be considered as the superposition of an external homogeneous and non-porous layer (outer bark) and a porous substructure layer (inner bark). This work is a first step for the future development of bio-based biomimetic wood coatings. The film had a bark-like appearance and its total density, bulk density and porosity were similar to values measured in natural bark. Furthermore, the structural characteristics of the studied film, namely specific surface area (BET) and pore size distribution, as well as the performance of the water adsorption ability were investigated and discussed.
High-quality rendering of spatial sound fields in real-time is becoming increasingly important with the steadily growing interest in virtual and augmented reality technologies. Typically, a spherical microphone array (SMA) is used to capture a spatial sound field. The captured sound field can be reproduced over headphones in real-time using binaural rendering, virtually placing a single listener in the sound field. Common methods for binaural rendering first spatially encode the sound field by transforming it to the spherical harmonics domain and then decode the sound field binaurally by combining it with head-related transfer functions (HRTFs). However, these rendering methods are computationally demanding, especially for high-order SMAs, and require implementing quite sophisticated real-time signal processing. This paper presents a computationally more efficient method for real-time binaural rendering of SMA signals by linear filtering. The proposed method allows representing any common rendering chain as a set of precomputed finite impulse response filters, which are then applied to the SMA signals in real-time using fast convolution to produce the binaural signals. Results of the technical evaluation show that the presented approach is equivalent to conventional rendering methods while being computationally less demanding and easier to implement using any real-time convolution system. However, the lower computational complexity goes along with lower flexibility. On the one hand, encoding and decoding are no longer decoupled, and on the other hand, sound field transformations in the SH domain can no longer be performed. Consequently, in the proposed method, a filter set must be precomputed and stored for each possible head orientation of the listener, leading to higher memory requirements than the conventional methods. As such, the approach is particularly well suited for efficient real-time binaural rendering of SMA signals in a fixed setup where usually a limited range of head orientations is sufficient, such as live concert streaming or VR teleconferencing.
We study p-adic L-functions Lp(s, 휒) for Dirichlet characters 휒. We show that Lp(s, 휒) has a Dirichlet series expansion for each regularization parameter c that is prime to p and the conductor of 휒. The expansion is proved by transforming a known formula for p-adic L-functions and by controlling the limiting behavior. A fnite number of Euler factors can be factored of in a natural manner from the p-adic Dirichlet series. We also provide an alternative proof of the expansion using p-adic measures and give an explicit formula for the values of the regularized Bernoulli distribution. The result is particularly simple for c = 2, where we obtain a Dirichlet series expansion that is similar to the complex case.
In Latin America and the Caribbean, river restoration projects are increasing, but many lack strategic planning and monitoring. We tested the applicability of a rapid visual social–ecological stream assessment method for restoration planning, complemented by a citizen survey on perceptions and uses of blue and green infrastructure. We applied the method at three urban streams in Jarabacoa (Dominican Republic) to identify and prioritize preferred areas for nature-based solutions. The method provides spatially explicit information for strategic river restoration planning, and its efficiency makes it suitable for use in data-poor contexts. It identifies well-preserved, moderately altered, and critically impaired areas regarding their hydromorphological and socio-cultural conditions, as well as demands on green and blue infrastructure. The transferability of the method can be improved by defining reference states for assessing the hydromorphology of tropical rivers, refining socio-cultural parameters to better address river services and widespread urban challenges, and balancing trade-offs between ecological and social restoration goals.
During spaceflight, humans experience a variety of physiological changes due to deviations from familiar earth conditions. Specifically, the lack of gravity is responsible for many effects observed in returning astronauts. These impairments can include structural as well as functional changes of the brain and a decline in cognitive performance. However, the underlying physiological mechanisms remain elusive. Alterations in neuronal activity play a central role in mental disorders and altered neuronal transmission may also lead to diminished human performance in space. Thus, understanding the influence of altered gravity at the cellular and network level is of high importance. Previous electrophysiological experiments using patch clamp techniques and calcium indicators have shown that neuronal activity is influenced by altered gravity. By using multi-electrode array (MEA) technology, we advanced the electrophysiological investigation covering single-cell to network level responses during exposure to decreased (micro-) or increased (hyper-) gravity conditions. We continuously recorded in real-time the spontaneous activity of human induced pluripotent stem cell (hiPSC)-derived neural networks in vitro. The MEA device was integrated into a custom-built environmental chamber to expose the system with neuronal cultures to up to 6 g of hypergravity on the Short-Arm Human Centrifuge at the DLR Cologne, Germany. The flexibility of the experimental hardware set-up facilitated additional MEA electrophysiology experiments under 4.7 s of high-quality microgravity (10–6 to 10–5 g) in the Bremen drop tower, Germany. Hypergravity led to significant changes in activity. During the microgravity phase, the mean action potential frequency across the neural networks was significantly enhanced, whereas different subgroups of neurons showed distinct behaviors, such as increased or decreased firing activity. Our data clearly demonstrate that gravity as an environmental stimulus triggers changes in neuronal activity. Neuronal networks especially reacted to acute changes in mechanical loading (hypergravity) or de-loading (microgravity). The current study clearly shows the gravity-dependent response of neuronal networks endorsing the importance of further investigations of neuronal activity and its adaptive responses to micro- and hypergravity. Our approach provided the basis for the identification of responsible mechanisms and the development of countermeasures with potential implications on manned space missions.
The European heating sector is currently heavily dominated by fossil fuels. Composting is a naturally occurring process in which heat is liberated from the composting substrate at a higher rate than the process needs to support itself. This difference could be harnessed for low-heat applications such as residential consumption, alleviating some of the impacts fossil fuel emissions represent. In this study, the composting heat recovery reported in the literature was compared to the energy demand for space and water heating in four European countries. A review of potential heat production from the waste representative of the residential sector was performed. We found that the theoretically recoverable composting heat does not significantly reduce the need for district heating. However, it can significantly reduce the energy demand for water heating, being able to supply countries such as Greece with between 36% and 100% of the yearly hot water demand, or 12% to 53% of the yearly hot water of countries such as Switzerland, depending on the efficiency of heat recovery.
The Production of Isophorone
(2023)
Isophorone is a technically important compound used as a high-boiling-point solvent for coatings, adhesives, etc., and it is used as a starting material for various valuable compounds, including isophorone diisocyanate, a precursor for polyurethanes. For over 80 years, isophorone has been synthesized via base-catalyzed self-condensation of acetone. This reaction has a complex reaction mechanism with numerous possible reaction steps including the formation of isophorone, triacetone dialcohol, and ketonic resins. This review provides an overview of the different production processes of isophorone in liquid- and vapor-phase and reviews the literature-reported selectivity toward isophorone achieved using different reaction parameters and catalysts.
Porous polymer membranes substantially contribute to an acceleration of sustainability transformation based on the energy efficient separation of liquid and gaseous mixtures. This rapid shift toward sustainable industrial processes leads to an increased demand for specifically tailored membranes. In order to predict membrane performance factors like permeability, selectivity and durability, the membrane formation process by film casting and phase inversion needs to be understood further. In recent years, computational models of the membrane formation process have been studied intensely. Their high spatial and temporal resolution allows a detailed quantitative description of phase inversion phenomena. New experimental techniques complement this development, as they provide quantitative data, e.g., on compositional changes of the polymer solution during membrane formation as well as the kinetic progression of the phase separation process. This state-of-the-art review compiles computational and experimental approaches that characterize the phase inversion process. We discuss how this methodological pluralism is necessary for improving the tailoring of membrane parameters, but that it is unlikely to be the way to the ultimate goal of a complete description of the evolution of the membrane structure from the initial demixing to the final solidification. Alternatively, we formulate an approach that includes a database of standardized and harmonized membrane performance data based on previously publicized data, as well as the application of artificial neural networks as a new powerful tool to link membrane production parameters to membrane performance.
Agents with antifungal activity play a vital role as therapeutics in health care, as do fungicides in agriculture. Effectiveness, toxicological profile, and eco-friendliness are among the properties used to select suitable substances. Furthermore, a steady supply of new agents with different modes of action is required to counter the well-known potential of human and phyto-pathogenic fungi to develop resistance against established antifungals. Here, we use an in vitro growth assay to investigate the activity of the calcineurin inhibitor tacrolimus in combination with the commercial fungicides cyproconazole and hymexazol, as well as with two earlier reported novel {2-(3-R-1H-1,2,4-triazol-5-yl)phenyl}amines, against the fungi Aspergillus niger, Colletotrichum higginsianum, Fusarium oxysporum and the oomycete Phytophthora infestans, which are notoriously harmful in agriculture. When tacrolimus was added in a concentration range from 0.25 to 25 mg/L to the tested antifungals (at a fixed concentration of 25 or 50 mg/L), the inhibitory activities were distinctly enhanced. Molecular docking calculations revealed triazole derivative 5, (2-(3-adamantan-1-yl)-1H-1,2,4-triazol-5-yl)-4-chloroaniline), as a potent inhibitor of chitin deacetylases (CDA) of Aspergillus nidulans and A. niger (AnCDA and AngCDA, respectively), which was stronger than the previously reported polyoxorin D, J075-4187, and chitotriose. The results are discussed in the context of potential synergism and molecular mode of action.
Hydroxybenzene, commonly known as phenol, is one of the most important organic commodity chemicals. To produce phenol, the cumene process is the most used process worldwide. A crucial step in this process is the Hock rearrangement, which has a major impact on the overall cumene consumption rate and determines the safety level of the process. The most used catalyst for the cleavage of cumene hydroperoxide (CHP) is sulfuric acid. Besides its strong corrosive property, which increases plant investment costs, it also requires neutralization after the decomposition step to prevent side reactions. In this study, we show that high-temperature-treated Linde Type X (LTX) zeolites exhibit a high activity for the peroxide cleavage step. In addition, the structure–activity relationship responsible for this good performance in the reaction system of the HOCK rearrangement was investigated. XRPD analyses revealed the formation of a new phase after temperature treatment above 900 °C. The Si/Al ratio determined by EDX suggested the formation of extra-framework aluminum, which was confirmed by solid-state NMR analysis. The newly formed extra-framework aluminum was found to be responsible for the high catalytic activity. BET analyses showed that the surface area drops at higher calcination temperatures. This leads to a lower catalytic activity for most known reactions. However, for this study, no decrease in activity has been observed. The newfound material shows extraordinarily high activity as a catalyst in the HOCK cleavage and has the potential to be a heterogeneous alternative to sulfuric acid for this reaction.
Due to its location at the south-west coast of Ireland County (Co.) Cork is frequently affected by post tropical cyclones (PTCs). There have been several records of these post hurricanes in the past with the last severe PTC being Hurricane Ophelia in 2017. It caused severe disruption in the whole country, especially in Co. Cork with several thousand people without water, power and mobile service for up to 10 days and thousands of uprooted trees which blocked roads. PTCs, like Ophelia, will become more frequent under climate change conditions due to warmer sea surface temperatures and decreased vertical wind shear. Hence, hurricanes can reach northern latitudes more easily and have a higher chance of making landfall in Co. Cork. This thesis assesses the risk perception towards natural hazards (NHs) and the perception of the risk communication of hurricane Ophelia by the citizens of Co. Cork and suggests improvements in communication based on the people’s perception. This was achieved by conducting a standardised survey to analyse the perception. The risk communication chain, its content and media involved were evaluated with interviews with professionals involved in risk management in Ireland. Improvement suggestions were extracted of the survey and the expert interviews as well and have been ranked by the participating experts according to their importance. The people of Co. Cork are not overly concerned about being affected by NHs. The three hazards they feel threatened by most, after Ophelia hit the country, are storms, river floodings and hurricanes. Before Ophelia made landfall, they only ranked hurricanes in the 8th place (out of 8). Ergo, after experiencing Ophelia people are much more aware of hurricane risk in Ireland. People were very satisfied with the information they received during Ophelia. The improvements they wished for are: 1) information on how to deal with and how to prepare for impacts of the storm, 2) the impacts that can be expected locally and 3) information where to go to in case of severe impact to property. These are mostly in line with the improvements the experts ranked as most important for Cork. Experts voted the suggestion to include information on behavioural advice into risk communication before the NH hits and advice on how to organise for impacts afterwards as their number one priority. Their second rank is to have education and training for the citizens in Cork. On third place they voted for a change to impact forecasting. Even there are no central buildings or shelters available in Co. Cork, this improvement suggestion was only voted on rank 13 by the experts (out of 14). Having a participatory approach in risk communication can overcome the discrepancies between the wishes of the population and the ones of the experts and would lead to a better understanding of all stakeholders involved in risk communication and can reduce vulnerability of the people in Co. Cork to the impacts of NHs. The implementation of these activities would be in line with best practice examples and would support the guidelines of the Irish Framework for Major Emergency Management.
Despite intensive research over the last three decades, it has not yet been possible to bring an effective vaccine against human immunodeficiency virus (HIV) and the resulting acquired immunodeficiency syndrome (AIDS) to market. Virus-like particles (VLP) are a promising approach for efficient and effective vaccination and could play an important role in the fight against HIV. For example, HEK293 (human embryo kidney) cells can be used to produce virus-like particles. In this context, given the quality-by-design (QbD) concept for manufacturing, a digital twin is of great importance for the production of HIV-Gag-formed VLPs. In this work, a dynamic metabolic model for the production of HIV-Gag VLPs was developed and validated. The model can represent the VLP production as well as the consumption or formation of all important substrates and metabolites. Thus, in combination with already described process analytical technology (PAT) methods, the final step towards the implementation of a digital twin for process development and design, as well as process automation, was completed.
This study aimed to simulate the sector-coupled energy system of Germany in 2030 with the restriction on CO2 emission levels and to observe how the system evolves with decreasing emissions. Moreover, the study presented an analysis of the interconnection between electricity, heat and hydrogen and how technologies providing flexibility will react when restricting CO2 emissions levels. This investigation has not yet been carried out with the technologies under consideration in this study. It shows how the energy system behaves under different set boundaries of CO2 emissions and how the costs and technologies change with different emission levels. The study results show that the installed capacities of renewable technologies constantly increase with higher limitations on emissions. However, their usage rates decreases with low CO2 emission levels in response to higher curtailed energy. The sector-coupled technologies behave differently in this regard. Heat pumps show similar behaviour, while the electrolysers usage rate increases with more renewable energy penetration. The system flexibility is not primarily driven by the hydrogen sector, but in low CO2 emission level scenarios, the flexibility shifts towards the heating sector and electrical batteries.
Electroplating generates high volumes of rinse water that is contaminated with heavy metals. This study presents an approach for direct metal recovery and recycling from simulated rinse water, made up of an electroplating electrolyte used in industry, using reverse osmosis (RO). To simulate the real industrial application, the process was examined at various permeate fluxes, ranging from 3.75 to 30 L·m−2·h−1 and hydraulic pressures up to 80 bar. Although permeance decreased significantly with increasing water recovery, rejections of up to 93.8% for boric acid, >99.9% for chromium and 99.6% for sulfate were observed. The final RO retentate contained 8.40 g/L chromium and was directly used in Hull cell electroplating tests. It was possible to deposit cold-hued chromium layers under a wide range of relevant current densities, demonstrating the reusability of the concentrate of the rinsing water obtained by RO.
Thioredoxin (Trx) overexpression is known to be a cause of chemotherapy resistance in various tumor entities. However, Trx effects on resistance are complex and depend strictly on tissue type. In the present study, we analyzed the impact of the Trx system on intrinsic chemoresistance of human glioblastoma multiforme (GBM) cells to cytostatic drugs. Resistance of GBM cell lines and primary cells to drugs and signaling inhibitors was assessed by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assays. Impact of Trx inhibition on apoptosis was investigated by proteome profiling of a subset of proteins and annexin V apoptosis assays. Trx-interacting protein (TXNIP) was overexpressed by transfection and protein expression was determined by immunoblotting. Pharmacological inhibition of Trx by 1-methyl-2-imidazolyl-disulfide (PX-12) reduced viability of three GBM cell lines, induced expression of active caspase-3, and reduced phosphorylation of AKT-kinase and expression of β-catenin. Sensitivity to cisplatin could be restored by both PX-12 and recombinant expression of the upstream Trx inhibitor TXNIP, respectively.
In addition, PX-12 also sensitized primary human GBM cells to temozolomide. Combined inhibition of Trx and the phosphatidylinositide 3-kinase (PI3K) pathway resulted in massive cell death. We conclude that the Trx system and the PI3K pathway act as a sequential cascade and could potentially present a new drug target.
Microphone arrays consisting of sensors mounted on the surface of a rigid, spherical scatterer are popular tools for the capture and binaural reproduction of spatial sound scenes. However, microphone arrays with a perfectly spherical body and uniformly distributed microphones are often impractical for the consumer sector, in which microphone arrays are generally mounted on mobile and wearable devices of arbitrary geometries. Therefore, the binaural reproduction of sound fields captured with arbitrarily shaped microphone arrays has become an important field of research. In this work, we present a comparison of methods for the binaural reproduction of sound fields captured with non-spherical microphone arrays. First, we evaluated equatorial microphone arrays (EMAs), where the microphones are distributed on an equatorial contour of a rigid, spherical 1.
Second, we evaluated a microphone array with six microphones mounted on a pair of glasses. Using these two arrays, we conducted two listening experiments comparing four rendering methods based on acoustic scenes captured in different rooms2. The evaluation includes a microphone-based stereo approach (sAB stereo), a beamforming-based stereo approach (sXY stereo), beamforming-based binaural reproduction (BFBR), and BFBR with binaural signal matching (BSM). Additionally, the perceptual evaluation included binaural Ambisonics renderings, which were based on measurements with spherical microphone arrays. In the EMA experiment we included a fourth-order Ambisonics rendering, while in the glasses array experiment we included a second-order Ambisonics rendering. In both listening experiments in which participants compared all approaches with a dummy head recording we applied non-head-tracked binaural synthesis, with sound sources only in the horizontal plane. The perceived differences were rated separately for the attributes timbre and spaciousness. Results suggest that most approaches perform similarly to the Ambisonics rendering. Overall, BSM, and microphone-based stereo were rated the best for EMAs, and BFBR and microphone-based stereo for the glasses array.
Abstract
(−)‐Menthol is one of the most popular aroma compounds worldwide. While in the past mostly extracted from mint plants, today (−)‐menthol synthesis from other raw materials is becoming more relevant. Common starting materials for menthol synthesis are m‐cresol, citral and myrcene, but also substrates like menthone, mono‐ and bicyclic terpenes and terpenoids have been used for this purpose in the past. As for many applications (−)‐menthol of high purity is required, asymmetric syntheses and enantiomeric resolution of obtained raw products are applied for menthol production. This review gives an overview on the most important synthetic menthol production processes of the companies Symrise, Takasago and BASF and relevant literature in the field of menthol synthesis with a focus on the last 20 years.
In water electrolyzers, polymer electrolyte membranes (PEMs) such as Nafion can accumulate cations stemming from salt impurities in the water supply, which leads to severe cell voltage increases. This combined experimental and computational study discusses the influence of sodium ion poisoning on the ionic conductivity of Nafion membranes and the ion transport in a thereon based water electrolysis cell. Conductivities of Nafion and aqueous solutions with the same amount of dissolved cations are measured with impedance spectroscopy and compared with respect to Nafion’s microstructure. The dynamic behavior of the voltage of a water electrolysis cell is characterized as a function of the sodium ion content and current density, showing the differences of the ion transport at alternating and direct currents. These experimental results are elucidated with a physical ion transport model for sodium ion poisoned Nafion membranes, which describes a proton depletion and sodium ion accumulation at the cathode. During proton depletion, the cathodic hydrogen evolution is maintained by the water reduction that forms hydroxide ions. Together with sodium ions from the membrane, the formed hydroxide ions can diffuse pairwise into the water supply, so that the membrane’s sodium ions can be at least partly be replaced with anodically formed protons.
Air-blast loading is a serious threat to military and civil vehicles, buildings, containers, and cargo. Applications of sandwich-structured composites have attracted increasing interest in modern lightweight design and in the construction of dynamic loading regimes due to their high resistance against blast and ballistic impacts. The functional properties of such composites are determined by the interplay of their face sheet material and the employed core topology. The core topology is the most important parameter affecting the structural behavior of sandwich composites. Therefore, this contribution presents a thorough numerical investigation of different core topologies in sandwich-structured composites subjected to blast loading. Special emphasis is put on prismatic and lattice core topologies displaying auxetic and classical non-auxetic deformation characteristics in order to illustrate the beneficial properties of auxetic core topologies. Their dynamic responses, elastic and plastic deformations, failure mechanisms, and energy absorption capabilities are numerically analyzed and compared. The numerical studies are performed by means of the commercial finite element code ABAQUS/Explicit, including a model for structural failure.
Conventional individual head-related transfer function (HRTF) measurements are demanding in terms of measurement time and equipment. For more flexibility, free body movement (FBM) measurement systems provide an easy-to-use way to measure full-spherical HRTF datasets with less effort. However, having no fixed measurement installation implies that the HRTFs are not sampled on a predefined regular grid but rely on the individual movements of the subject. Furthermore, depending on the measurement effort, a rather small number of measurements can be expected, ranging, for example, from 50 to 150 sampling points. Spherical harmonics (SH) interpolation has been extensively studied recently as one method to obtain full-spherical datasets from such sparse measurements, but previous studies primarily focused on regular full-spherical sampling grids. For irregular grids, it remains unclear up to which spatial order meaningful SH coefficients can be calculated and how the resulting interpolation error compares to regular grids. This study investigates SH interpolation of selected irregular grids obtained from HRTF measurements with an FBM system. Intending to derive general constraints for SH interpolation of irregular grids, the study analyzes how the variation of the SH order affects the interpolation results. Moreover, the study demonstrates the importance of Tikhonov regularization for SH interpolation, which is popular for solving ill-posed numerical problems associated with such irregular grids. As a key result, the study shows that the optimal SH order that minimizes the interpolation error depends mainly on the grid and the regularization strength but is almost independent of the selected HRTF set. Based on these results, the study proposes to determine the optimal SH order by minimizing the interpolation error of a reference HRTF set sampled on the sparse and irregular FBM grid. Finally, the study verifies the proposed method for estimating the optimal SH order by comparing interpolation results of irregular and equivalent regular grids, showing that the differences are small when the SH interpolation is optimally parameterized.
Circular economy (CE) has received considerable interest in recent years as a strategy to resolve some of our modern urban resource challenges, and circular city models often incorporate systems of urban agriculture in their design. Much work has analyzed the benefits of urban agriculture for creating a resilient food system and as a strategy for supporting urban green space and social cohesion, however, the contributions from business models that operate within urban agriculture have not been thoroughly studied. Many urban agriculture businesses often claim high levels of resource recycling and material circularity, though whether a resource efficiency throughout the entire product lifetime (including energy and material footprint for the cultivation equipment) in comparison to current industrial strategies is truly feasible or even possible is still to be debated. This thesis builds upon work that incorporates social dimensions of CE definitions and begins to research whether the potential resource efficiency contradiction can be justified as to make urban agriculture a valid approach for circular city design. This study examined an urban mushroom farm that implements a circular business model. A qualitative summary of the business operations and resource flows were unpacked and sorted into 24 socio-economic contributions based on their interpreted relevance. The interpreted data shows that an urban agriculture business model can contribute to the building blocks of a CE through economic, ecological, social, and spatial contributions. While these contributions can contribute positively to the operationalization of CE, potential trade-offs regarding resource efficiency, use of urban space, and investment priorities need to be considered and addressed to avoid a possible watering down or greenwashing of the CE concept.
The management of the liquid fraction of digestate produced from the anaerobic digestion of biodegradable municipal solid waste is a difficult affair, as its land application is limited due to high ammonium concentrations and the municipal waste that water treatment plants struggle to treat due to high pollutant loads. The amount of leachate and the pollutant load in the leachate produced by landfills usually decreases with the time, which increases the capacity of landfill leachate treatment plants (LLTPs) to treat additional wastewater. In order to solve the above two challenges, the co-treatment of landfill leachate and the liquid fraction of anaerobic digestate in an industrial-scale LLTP was investigated along with the long-term impacts of the liquid fraction of anaerobic digestate on biocoenosis and its impact on LLTP operational expenses. The co-treatment of landfill leachate and liquid fraction of anaerobic digestate was compared to conventional leachate treatment in an industrial-scale LLTP, which included the use of two parallel lanes (Lane-1 and Lane-2). The average nitrogen removal efficiencies in Lane-1 (co-treatment) were 93.4%, 95%, and 92%, respectively, for C/N ratios of 8.7, 8.9, and 9.4. The average nitrogen removal efficiency in Lane-2 (conventional landfill leachate treatment), meanwhile, was 88%, with a C/N ratio of 6.5. The LLTP’s average chemical oxygen demand (COD) removal efficiencies were 63.5%, 81%, and 78% during phases one, two, and three, respectively. As the volume ratios of the liquid fraction of anaerobic digestate increased, selective oxygen uptake rate experiments demonstrated the dominance of heterotrophic bacteria over ammonium and nitrite-oxidising organisms. The inclusion of the liquid fraction of anaerobic digestate during co-treatment did not cause a significant increase in operational resources, i.e., oxygen, the external carbon source, activated carbon, and energy.
To realize a reliable and cost-effective application of high-temperature superconductive (HTS) equipment at high-voltage (HV) levels, the influence of thermally induced gas bubbles on the dielectric strength of different solid insulating materials in liquid nitrogen (LN2) was investigated. A heatable copper tape electrode arrangement was developed simulating HTS tapes with insulation in between. AC breakdown measurements were performed without and with forced boiling on insulating papers, polypropylene laminated paper (PPLP) and polyimide (PI) films. Under nucleate boiling the influence of bubbles on the dielectric strength of all materials was not significant. However under film boiling the dielectric strength of the insulating papers decreased to a level comparable to their dielectric strength in air, demonstrating the insufficient impregnation of porous materials under film boiling. For PI there was no degradation at all. PPLP retained about 70% of its basic dielectric strength in LN2.
AbstractThis paper discusses the comparison of two methods to achieve thermal comfort utilising air conditioning (AC) system in a small indoor space – adaptive control and fuzzy control. Thermal comfort indoors is performed to provide comfortability individually or for a group of people. Due to the small indoor space which usually a bit cramped, crowded and less airy, the ambience can be very uncomfortable either for doing sedentary or active work, thus the AC system can be very useful to provide thermal comfort. Both methods can be utilised depending on how thermal comfort is viewed and how the level of thermal comfort is decided. Every method has its own advantage and limitations, and will be covered in this paper as well.
Climate change includes the change of the long-term average values and the change of the tails of probability density functions, where the extreme events are located. However, obtaining average values are more straightforward than the high temporal resolution information necessary to catch the extreme events on those tails. Such information is difficult to get in areas lacking sufficient rain stations. Thanks to the development of Satellite Precipitation Estimates with a daily resolution, this problem has been overcome, so Extreme Precipitation Indices (EPI) can be calculated for the entire Colombian territory. However, Colombia is strongly affected by the ENSO (El Niño—Southern Oscillation) phenomenon. Therefore, it is pertinent to ask if the EPI’s long-term change due to climate change is more critical than the anomalies due to climate variability induced by the warm and cold phases of ENSO (El Niño and La Niña, respectively). In this work, we built EPI annual time series at each grid-point of the selected Satellite Precipitation Estimate (CHIRPSv2) over Colombia to answer the previous question. Then, the Mann-Whitney-Wilcoxon test was used to compare the samples drawn in each case (i.e., change tests due to both long-term and climatic variability). After performing the analyses, we realized that the importance of the change depends on the region analyzed and the considered EPI. However, some general conclusions became evident: during El Niño years (La Niña), EPI’s anomaly follows the general trend of reduction -drier conditions- (increase; -wetter conditions-) observed in Colombian annual precipitation amount, but only on the Pacific, the Caribbean, and the Andean region. In the Eastern plains of Colombia (Orinoquía and Amazonian region), EPI show a certain insensitivity to change due to climatic variability. On the other hand, EPI’s long-term changes in the Pacific, the Caribbean, and the Andean region are spatially scattered. Still, long-term changes in the eastern plains have a moderate spatial consistency with statistical significance.
Abstract
Two types (with and without a hydrolysis stabilizer) of polyamide 6.6 (PA6.6) reinforced with 30% w/w glass fibres were examined against the influence of automotive cooling fluids, e.g. ethylene glycol aqueous solutions. The overall goal was to find a methodology to compare the performance of PA6.6 materials against the impacts of the hydrolysis environment. The stabilizer effect on the hydrolytic resistance of the materials was assessed using tensile tests according to ISO 527, and their strain‐at‐break values were evaluated in more detail. The degradation mechanism of both PA types was monitored by infrared spectroscopy and SEM. The material lifetime was described by the Arrhenius equation. The results show that the hydrolysis stabilizer operates effectively at low temperature but exhibits weak performance above 130 °C, which is explained by faster consumption of the stabilizing agent. © 2021 The Authors. Polymer International published by John Wiley & Sons Ltd on behalf of Society of Industrial Chemistry.
In this work, supported cellulose acetate (CA) mixed matrix membranes (MMMs) were prepared and studied concerning their gas separation behaviors. The dispersion of carbon nanotube fillers were studied as a factor of polymer and filler concentrations using the mixing methods of the rotor–stator system (RS) and the three-roll-mill system (TRM). Compared to the dispersion quality achieved by RS, samples prepared using the TRM seem to have slightly bigger, but fewer and more homogenously distributed, agglomerates. The green γ-butyrolactone (GBL) was chosen as a polyimide (PI) polymer-solvent, whereas diacetone alcohol (DAA) was used for preparing the CA solutions. The coating of the thin CA separation layer was applied using a spin coater. For coating on the PP carriers, a short parameter study was conducted regarding the plasma treatment to affect the wettability, the coating speed, and the volume of dispersion that was applied to the carrier. As predicted by the parameter study, the amount of dispersion that remained on the carriers decreased with an increasing rotational speed during the spin coating process. The dry separation layer thickness was varied between about 1.4 and 4.7 μm. Electrically conductive additives in a non-conductive matrix showed a steeply increasing electrical conductivity after passing the so-called percolation threshold. This was used to evaluate the agglomeration behavior in suspension and in the applied layer. Gas permeation tests were performed using a constant volume apparatus at feed pressures of 5, 10, and 15 bar. The highest calculated CO2/N2 selectivity (ideal), 21, was achieved for the CA membrane and corresponded to a CO2 permeability of 49.6 Barrer.
The oxidation of cumene and following cleavage of cumene hydroperoxide (CHP) with sulfuric acid (Hock rearrangement) is still, by far, the dominant synthetic route to produce phenol. In 2020, the global phenol market reached a value of 23.3 billion US$ with a projected compound annual growth rate of 3.4% for 2020–2025. From ecological and economical viewpoints, the key step of this process is the cleavage of CHP. One sought-after way to likewise reduce energy consumption and waste production of the process is to substitute sulfuric acid with heterogeneous catalysts. Different types of zeolites, silicon-based clays, heteropoly acids, and ion exchange resins have been investigated and tested in various studies. For every type of these solid acid catalysts, several materials were found that show high yield and selectivity to phenol. In this mini-review, first a brief introduction and overview on the Hock process is given. Next, the mechanism, kinetics, and safety aspects are summarized and discussed. Following, the different types of heterogeneous catalysts and their performance as catalyst in the Hock process are illustrated. Finally, the different approaches to substitute sulfuric acid in the synthetic route to produce phenol are briefly concluded and a short outlook is given.
Different methods have been proposed for in situ root-length density (RLD) measurement. One widely employed is the time-consuming sampling of soil cores or monoliths (MO). The profile wall (PW) method is a less precise, but faster and less laborious alternative. However, depth-differentiated functions to convert PW RLD estimates to MO RLD measurements have not yet been reported. In this study, we perform a regression analysis to relate PW results to MO results and determine whether calibration is possible for distinct crop groups (grasses, brassicas and legumes) consisting of pure and mixed stands, and whether soil depth affects this calibration. The methods were applied over two years to all crop groups and their absolute and cumulative RLD were compared using a linear (LR) and multiple linear (MLR) regression. PW RLD was found to highly underestimate MO RLD in absolute values and in highly rooted areas. However, a close agreement between both methods was found for cumulative root-length (RL) when applying MLR, highlighting the influence of soil depth. The level of agreement between methods varied strongly with depth. Therefore, the application of PW as the main RLD estimation method can provide reliable estimates of cumulative root distribution traits of cover crops.
The increase in greenhouse gas emissions, mainly due to the burning of fossil fuels and land use change, has led to changes in the global climate. Agriculture is one of the economic sectors most vulnerable to the impacts generated by climate change. For this reason, the challenge facing humanity today is to develop innovative solutions to address the complexity of agricultural sustainability.
On the other hand, sugarcane is one of the crops that emits the most pollutants into the atmosphere, mainly due to the burning of sugarcane before and after harvesting. Most of these atmospheric pollutants are precursors of climate change and have an impact on the health and quality of life of communities. Moreover, this agricultural practice causes the gradual deterioration of the soil, directly affecting sugarcane production. Consequently, several sugarcane-producing countries have established regulations or dispositions to eliminate this agricultural practice, and one option to eliminate it is the mechanization of harvesting. However, its implementation implies social, environmental, and economic impacts that must be analyzed systemically to avoid potential failures during the technological transition process. It is for this reason that this research, through the MICMAC method, focused on identifying the variables associated with the reduction of sugarcane burning in Campos dos Goytacazes and Tamasopo, to subsequently analyze their direct and indirect interrelationship, and, thus, determine the opportunities and limitations of each locality for the reduction of sugarcane burning.
Through this analysis, it became evident that although the technological transition is an imminent step for the sustainability of sugarcane cultivation, certain factors such as legislation, technological innovation, and the perception of the stakeholders regarding the consequences of sugarcane burning, is what defines in the study sites the speed and subsequent success of this process of change towards green harvesting.
Table Tennis Tutor: Forehand Strokes Classification Based on Multimodal Data and Neural Networks
(2021)
Beginner table-tennis players require constant real-time feedback while learning the fundamental techniques. However, due to various constraints such as the mentor’s inability to be around all the time, expensive sensors and equipment for sports training, beginners are unable to get the immediate real-time feedback they need during training. Sensors have been widely used to train beginners and novices for various skills development, including psychomotor skills. Sensors enable the collection of multimodal data which can be utilised with machine learning to classify training mistakes, give feedback, and further improve the learning outcomes. In this paper, we introduce the Table Tennis Tutor (T3), a multi-sensor system consisting of a smartphone device with its built-in sensors for collecting motion data and a Microsoft Kinect for tracking body position. We focused on the forehand stroke mistake detection. We collected a dataset recording an experienced table tennis player performing 260 short forehand strokes (correct) and mimicking 250 long forehand strokes (mistake). We analysed and annotated the multimodal data for training a recurrent neural network that classifies correct and incorrect strokes. To investigate the accuracy level of the aforementioned sensors, three combinations were validated in this study: smartphone sensors only, the Kinect only, and both devices combined. The results of the study show that smartphone sensors alone perform sub-par than the Kinect, but similar with better precision together with the Kinect. To further strengthen T3’s potential for training, an expert interview session was held virtually with a table tennis coach to investigate the coach’s perception of having a real-time feedback system to assist beginners during training sessions. The outcome of the interview shows positive expectations and provided more inputs that can be beneficial for the future implementations of the T3.
Remote sensing applications of change detection are increasingly in demand for many areas of land use and urbanization, and disaster risk reduction. The Sendai Framework for Disaster Risk Reduction and the New Urban Agenda by the United Nations call for risk monitoring. This study maps and assesses the urban area changes of 23 Mexican-USA border cities with a remote sensing-based approach. A literature study on existing studies on hazard mapping and social vulnerability in those cities reveals a need for further studies on urban growth. Using a multi-modal combination of aerial, declassified (CORONA, GAMBIT, HEXAGON programs), and recent (Sentinel-2) satellite imagery, this study expands existing land cover change assessments by capturing urban growth back to the 1940s. A Geographic Information System and census data assessment results reveal that massive urban growth has occurred on both sides of the national border. On the Mexican side, population and area growth exceeds the US cities in many cases. In addition, flood hazard exposure has grown along with growing city sizes, despite structural river training. These findings indicate a need for more risk monitoring that includes remote sensing data. It has socio-economic implications, too, as the social vulnerability on Mexican and US sides differ. This study calls for the maintenance and expansion of open data repositories to enable such transboundary risk comparisons. Common vulnerability variable sets could be helpful to enable better comparisons as well as comparable flood zonation mapping techniques. To enable risk monitoring, basic data such as urban boundaries should be mapped per decade and provided on open data platforms in GIS formats and not just in map viewers.
Pluvial floods claimed more than 180 lives in Germany in July 2021, when a large and slow-moving storm system affected Germany and many neighbouring countries. The death tolls and damages were the highest since 1962 in Germany, and soon after, the crisis management was under public critique. This study has undertaken an online survey to understand crisis management better and identify lessons to learn. It has received a positive interest among operational relief forces and other helpers (n = 2264). The findings reveal an overall satisfaction with the operation in general as well as personal lessons learned. It also reveals shortcomings in many areas, ranging from information distribution, coordination, parallel ongoing COVID-19 pandemic, infrastructure resilience, and other factors. Just as well, areas for improvement of the crisis management system are suggested by the respondents. Cooperation and support by the affected population are perceived as positive. This helps to inform other areas of research that are necessary, such as studies on the perception by the affected people. The gaps in assessments of operational forces and some methodological constraints are discussed to advance future follow-up studies.
Linoleic acid hydroperoxides are versatile intermediates for the production of green note aroma compounds and bifunctional ω-oxo-acids. An enzyme cascade consisting of lipoxygenase, lipase and catalase was developed for one-pot synthesis of 13-hydroperoxyoctadecadienoic acid starting from safflower oil. Reaction conditions were optimized for hydroperoxidation using lipoxygenase 1 from Glycine max (LOX-1) in a solvent-free system. The addition of green surfactant Triton CG-110 improved the reaction more than two-fold and yields of >50% were obtained at linoleic acid concentrations up to 100 mM. To combine hydroperoxidation and oil hydrolysis, 12 lipases were screened for safflower oil hydrolysis under the reaction conditions optimized for LOX-1. Lipases from Candida rugosa and Pseudomonas fluorescens were able to hydrolyze safflower oil to >75% within 5 h at a pH of 8.0. In contrast to C. rugosa lipase, the enzyme from P. fluorescens did not exhibit a lag phase. Combination of P. fluorescens lipase and LOX-1 worked well upon LOX-1 dosage and a synergistic effect was observed leading to >80% of hydroperoxides. Catalase from Micrococcus lysodeikticus was used for in-situ oxygen production with continuous H2O2 dosage in the LOX-1/lipase reaction system. Foam generation was significantly reduced in the 3-enzyme cascade in comparison to the aerated reaction system. Safflower oil concentration was increased up to 300 mM linoleic acid equivalent and 13-hydroperoxides could be produced in a yield of 70 g/L and a regioselectivity of 90% within 7 h.
Water scarcity drives governments in arid and semi-arid regions to promote strategies for improving water use efficiency. Water-related research generally also plays an important role in the same countries and for the same reason. However, it remains unclear how to link the implementation of new government strategies and water-related research. This article’s principal objective is to present a novel approach that defines water-related research gaps from the point of view of a government strategy. The proposed methodology is based on an extensive literature review, followed by a systematic evaluation of the topics covered both in grey and peer-reviewed literature. Finally, we assess if and how the different literature sources contribute to the goals of the water strategy. The methodology was tested by investigating the impact of the water strategy of Jordan’s government (2008–2022) on the research conducted in the Azraq Basin, considering 99 grey and peer-reviewed documents. The results showed an increase in the number of water-related research documents from 37 published between 1985 and 2007 to 62 published between 2008 and 2018. This increase should not, however, be seen as a positive impact of increased research activity from the development of Jordan’s water strategy. In fact, the increase in water-related research activity matches the increasing trend in research production in Jordan generally. Moreover, the results showed that only about 80% of the documents align with the goals identified in the water strategy. In addition, the distribution of the documents among the different goals of the strategy is heterogeneous; hence, research gaps can be identified, i.e., goals of the water-strategy that are not addressed by any of the documents sourced. To foster innovative and demand-based research in the future, a matrix was developed that linked basin-specific research focus areas (RFAs) with the MWI strategy topics. In doing so, the goals that are not covered by a particular RFA are highlighted. This analysis can inspire researchers to develop and apply new topics in the Azraq Basin to address the research gaps and strengthen the connection between the RFAs and the strategy topics and goals. Moreover, the application of the proposed methodology can motivate future research to become demand-driven, innovative, and contribute to solving societal challenges.
The paper structure of historical prints is sort of a unique fingerprint. Paper with the same origin shows similar chain line distances. As the manual measurement of chain line distances is time consuming, the automatic detection of chain lines is beneficial. We propose an end-to-end trainable deep learning method for segmentation and parameterization of chain lines in transmitted light images of German prints from the 16th Century. We trained a conditional generative adversarial network with a multitask loss for line segmentation and line parameterization. We formulated a fully differentiable pipeline for line coordinates’ estimation that consists of line segmentation, horizontal line alignment, and 2D Fourier filtering of line segments, line region proposals, and differentiable line fitting. We created a dataset of high-resolution transmitted light images of historical prints with manual line coordinate annotations. Our method shows superior qualitative and quantitative chain line detection results with high accuracy and reliability on our historical dataset in comparison to competing methods. Further, we demonstrated that our method achieves a low error of less than 0.7 mm in comparison to manually measured chain line distances.
The paper focuses on a study of turbulence decay in flow with streamwise gradient. For the first time, an analytical solution of this problem was obtained based on the k‐ε model of turbulence in one‐dimensional (1D) approximation, as well as on the symmetry properties of the system of differential equations. Lie group technique enabled reducing the problem to a linear differential equation. The analytical solution enabled parametric studies, which are computationally cheap in comparison to CFD based simulations. The lattice Boltzmann method (LBM) in two‐dimensional approximation (2D) was used to validate the analytical results. Large eddy simulation (LES) Smagorinsky approach was used to close the LBM model. Computations revealed that the rate of turbulence decay is significantly different for the cases of positive and negative streamwise pressure gradient. The further comparisons showed that the analytical solution underpredicts the predictions by the numerical methodology, which can be attributed to the simplified problem statement used to derive the closed‐form analytical solution. Comparisons of calculations with experiments revealed that the theoretical models used in the study underpredict the measurements for flows with a positive pressure gradient. Hence it can be concluded that the LBM technique combined with the LES Smagorinsky model requires the further modification.
The production of pharmaceutical ingredients, intermediates and final products strongly depends on the utilization of water. Water is also required for the purification and preparation of reagents. Each specific application determines the respective water quality. In the European Union, the European Pharmacopeia (Ph. Eur.) contains the official standards that assure quality control of pharmaceutical products during their life cycle. According to this, the production of water for pharmaceutical use is mainly based on multi-stage distillation and membrane processes, especially, reverse osmosis. Membrane distillation (MD) could be an alternative process to these classical methods. It offers advantages in terms of energy demand and a compact apparatus design. In the following study, the preparation of pharmaceutical-grade water from tap water in a one-step process using MD is presented. Special emphasis is placed on the performance of two different module designs and on the selection of optimum process parameters.
Remote rural populations do not often have the luxury of viable multisource electricity generation systems. Considering fossil fuels for remote populated areas is not often a viable option due to the fuel transportation costs and the population’s socioeconomic status. Extending the grid is often economically prohibitive. This paper proposes possible ways in which Mali could increase the rate of population with access to electricity by 2050 using Low Emission Analysis Platform (LEAP) and geographical information tools. The current energy situation is assessed, and multiple demand and supply scenarios are created to find the most viable option in environmental and economic dimensions. A minimum of 50% reduction of biomass consumption in the residential sector and a maximum of 71% was achieved through the combination of grid extension and decentralized solar PV. Solar PV becomes the preferable option when enough time for the effects of electricity on income is given. When these effects are not present, solar PV is still a better option, as the amount of biomass replaced with electricity is reduced.
Currently, difficulties such as the depletion of fossil fuel resources and the associated environmental pollution have driven the rise of other energy systems based on green energy sources.
In this research, modeling and a viability study of grid-connected and islanded photovoltaic (PV) power systems for supplying the residential load in Mekelle City, Ethiopia, were carried out considering the country’s emerging utility tariff plan for 2021 and beyond. The technical viability of the proposed supply option was analyzed using PVGIS, PVWatts and HOMER Pro tool, while the economic and environmental optimization aspects were carried out using HOMER Pro. Sensitivity analyses and output comparisons among the three renewable energy simulation tools are presented.
The results showed that under the consideration of an incremental electricity tariff plan (up to 2021), the analyzed cost of energy of the grid/PV system is around 12% lower than the utility grid tariff. Moreover, we also found that by taking the continuous global solar PV cost reduction into account, the cost of energy of the modeled islanded operation of solar PV power units totally broke the grid tariff in Ethiopia after 2029 based on the tariff for 2021 and well before with the expected escalation of the grid tariff on an annual basis. The technical performance of the system realized through PVGIS and PVWatts was almost comparable to the HOMER Pro outputs. Thus, this investigation will offer a clear direction to the concerned target groups and policy developers in the evolution of PV power supply options throughout the technically viable locations in the country.
Due to reasons of sustainability and conservation of resources, polyurethane (PU)-based systems with preferably neutral carbon footprints are in increased focus of research and development. The proper design and development of bio-based polyols are of particular interest since such polyols may have special property profiles that allow the novel products to enter new applications. Sophorolipids (SL) represent a bio-based toolbox for polyol building blocks to yield diverse chemical products. For a reasonable evaluation of the potential for PU chemistry, however, further investigations in terms of synthesis, derivatization, reproducibility, and reactivity towards isocyanates are required. It was demonstrated that SL can act as crosslinker or as plasticizer in PU systems depending on employed stoichiometry. (ω-1)-hydroxyl fatty acids can be derived from SL and converted successively to polyester polyols and PU. Additionally, (ω-1)-hydroxyl fatty acid azides can be prepared indirectly from SL and converted to A/B type PU by Curtius rearrangement.
At the case study of the city of Cologne and the neighbouring Rhein‐Erft‐Kreis (a county), selected resilience aspects of critical infrastructure (CI) and cascading effects are analysed concerning major river floods. Using a Geographic Information System, the applicability of the approach is demonstrated using open source software and data, augmented by manual entries. This study demonstrates the feasibility and limitations of analysing lifeline features of interest for disaster risk and emergency management such as roads, bridges and electricity supply. By highlighting interdependencies of emergency services with CI such as roads, cascading effects of interconnected paths are shown. The findings indicate that in an extreme event flood scenario over 2,000 km of roads and eight bridges will be exposed to floods in the area of the rivers Rhine and Erft. This places huge demands on disaster and emergency management institutions and people affected and limits their resiliency.
An Analytical Investigation of Natural Convection of a Van Der Waals Gas over a Vertical Plate
(2021)
The study focused on a theoretical study of natural convection in a van der Waals gasnear a vertical plate. A novel simplified form of the van der Waals equation derived in the studyenabled analytical modeling of fluid flow and heat transfer. Analytical solutions were obtained forthe velocity and temperature profiles, as well as the Nusselt numbers. It was revealed that nonlineareffects considered by the van der Waals equation of state contribute to acceleration or decelerationof the flow. This caused respective enhancement or deterioration of heat transfer. Results for a vander Waals gas were compared with respective computations using an ideal gas model. Limits of theapplicability of the simplified van der Waals equations were pinpointed.
A test tool for Langton's ant-based algorithms is created. Among other things, it can create test files for the NIST-Statistical-Test-Suite. The test tool is used to investigate the invertibility, ring formation and randomness of 7 created models which are extensions of Langton’s ant. The models are examined to possibly use them as pseudo-random generator (PRG) or block cipher. All models use memories which are based on tori. This property is central, because this is how rings are formed in the first place and in addition the behavior of all models at the physical boundaries of the memory is clearly defined in this way. The different models have special properties which are also investigated. These include variable color sets, discrete convolution, multidimensionality, and the use of multiple ants, which are arranged fractal hierarchically and influence each other. The extensions convolution, multidimensional scalable and multidimensional scalable fractal ant colony are presented here for the first time. It is shown that well-chosen color sets and high-dimensional tori are particularly well suited as a basis for Langton's ant based PRGs. In addition, it is shown that a block cipher can be generated on this basis.
The main scope of this work is to develop nano-carbon-based mixed matrix celluloseacetate membranes (MMMs) for the potential use in both gas and liquid separation processes. Forthis purpose, a variety of mixed matrix membranes, consisting of cellulose acetate (CA) polymerand carbon nanotubes as additive material were prepared, characterized, and tested. Multi-walledcarbon nanotubes (MWCNTs) were used as filler material and diacetone alcohol (DAA) as solvent.The first main objective towards highly efficient composite membranes was the proper preparationof agglomerate-free MWCNTs dispersions. Rotor-stator system (RS) and ultrasonic sonotrode (USS)were used to achieve the nanofillers’ dispersion. In addition, the first results of the application of thethree-roll mill (TRM) technology in the filler dispersion achieved were promising. The filler material,MWCNTs, was characterized by scanning electron microscopy (SEM) and liquid nitrogen (LN2)adsorption-desorption isotherms at 77 K. The derivatives CA-based mixed matrix membranes werecharacterized by tensile strength and water contact angle measurements, impedance spectroscopy,gas permeability/selectivity measurements, and water permeability tests. The studied membranesprovide remarkable water permeation properties, 12–109 L/m2/h/bar, and also good separationfactors of carbon dioxide and helium separations. Specifically, a separation factor of 87 for 10%He/N2feed concentration and a selectivity value of 55.4 for 10% CO2/CH4feed concentrationwere achieved.
The use of nematic liquid crystal (LC) mixtures for microwave frequency applicationspresents a fundamental drawback: many of these mixtures have not been properly characterizedat these frequencies, and researchers do not have an a priori clear idea of which behavior they canexpect. This work is focused on developing a new procedure for the extraction of the main parametersof a nematic liquid crystal: dielectric permittivity and loss tangent at 11 GHz under differentpolarization voltages; splay elastic constantK11, which allows calculation of the threshold voltage(Vth); and rotational viscosityγ11, which allows calculating the response time of any arbitrary device.These properties will be calculated by using a resonator-based method, which is implementedwith a new topology of substrate integrated transmission line. The LC molecules should be rotated(polarized) by applying an electric field in order to extract the characteristic parameters; thus,the transmission line needs to have two conductors and low electric losses in order to preserve theintegrity of the measurements. This method was applied to a well-known liquid crystal mixture(GT3-23002 from MERCK) obtaining the permittivity and loss tangent versus bias voltage curves,the splay elastic constant, and the rotational viscosity of the mixture. The results validate the viabilityof the proposed method.
Mental illnesses in adolescence and young adulthood are steadily increasing. Thus,mental disorders represent an individual and societal challenge and an enormous health economicburden, creating an urgent need for research and action. Mental health problems are omnipresent inthe life of young people and the internet is the first resource, which helps them to understand theirsituation. Young people with migration background often have more difficulties accessing health careservices. Digital technologies offer an ideal opportunity for a low-threshold platform that addressesthe needs of young people. The current project “GeKo:mental” aims to design a multilingual websitefor Cologne-based adolescents and young adults that will enable them to obtain comprehensiveinformation about mental illness and health, treatment options and first contact points. To designthis website, this study aims to find out what kind of health information is needed and how itshould best be presented. Nine focus group discussions with adolescents and young adults withand without migration background (N = 68) were conducted; the focus group discussions took placeat schools, in an association for social youth work and in an cultural association, which is linkedto a mosque in Cologne, Germany. A qualitative content analysis was conducted on the gatheredmaterial. The participants reported concrete challenges and needs. The results will form the basis forthe development and design of a website.
Hydrogen is nowadays in focus as an energy carrier that is locally emission free. Especiallyin combination with fuel-cells, hydrogen offers the possibility of a CO2neutral mobility, providedthat the hydrogen is produced with renewable energy. Structural parts of automotive componentsare often made of steel, but unfortunately they may show degradation of the mechanical propertieswhen in contact with hydrogen. Under certain service conditions, hydrogen uptake into the appliedmaterial can occur. To ensure a safe operation of automotive components, it is therefore necessary toinvestigate the time, temperature and pressure dependent hydrogen uptake of certain steels, e.g., todeduct suitable testing concepts that also consider a long term service application. To investigate thematerial dependent hydrogen uptake, a tubular autoclave was set-up. The underlying paper describesthe set-up of this autoclave that can be pressurised up to 20 MPa at room temperature and can beheated up to a temperature of 250◦C, due to an externally applied heating sleeve. The second focusof the paper is the investigation of the pressure dependent hydrogen solubility of the martensiticstainless steel 1.4418. The autoclave offers a very fast insertion and exertion of samples and thereforehas significant advantages compared to commonly larger autoclaves. Results of hydrogen chargingexperiments are presented, that were conducted on the Nickel-martensitic stainless steel 1.4418.Cylindrical samples 3 mm in diameter and 10 mm in length were hydrogen charged within theautoclave and subsequently measured using thermal desorption spectroscopy (TDS). The resultsshow how hydrogen sorption curves can be effectively collected to investigate its dependence ontime, temperature and hydrogen pressure, thus enabling, e.g., the deduction of hydrogen diffusioncoefficients and hydrogen pre-charging concepts for material testing.
Bridging Gaps in Minimum Humanitarian Standards and Shelter Planning by Critical Infrastructures
(2021)
Current agendas such as the Sendai Framework for Disaster Risk Reduction or the Sustain-able Development Goals are demanding more integration of disaster risk management into otherthematic fields and relevant sectors. However, certain thematic fields such as shelter planning andcritical infrastructure have not been integrated yet. This article provides an analysis of minimumhumanitarian standards contained in the well-known Sphere handbook. Gaps are identified forseveral critical infrastructure services. Moreover, guidance on how to derive infrastructure or lifelineneeds has been found missing. This article analyses the missing service supply and infrastructureidentification items and procedures. The main innovation is a more integrative perspective on infras-tructure that can improve existing minimum humanitarian standards. It can guide the provision ofinfrastructure services to various types for different hazard scenarios, hence make humanitarian aidand shelter planning more sustainable in terms of avoiding infrastructure or lifeline shortages.
Ghana suffers from frequent power outages, which can be compensated by off-grid energysolutions. Photovoltaic-hybrid systems become more and more important for rural electrificationdue to their potential to offer a clean and cost-effective energy supply. However, uncertainties relatedto the prediction of electrical loads and solar irradiance result in inefficient system control and canlead to an unstable electricity supply, which is vital for the high reliability required for applicationswithin the health sector. Model predictive control (MPC) algorithms present a viable option to tacklethose uncertainties compared to rule-based methods, but strongly rely on the quality of the forecasts.This study tests and evaluates (a) a seasonal autoregressive integrated moving average (SARIMA)algorithm, (b) an incremental linear regression (ILR) algorithm, (c) a long short-term memory (LSTM)model, and (d) a customized statistical approach for electrical load forecasting on real load data of aGhanaian health facility, considering initially limited knowledge of load and pattern changes throughthe implementation of incremental learning. The correlation of the electrical load with exogenousvariables was determined to map out possible enhancements within the algorithms. Results showthat all algorithms show high accuracies with a median normalized root mean square error (nRMSE)<0.1 and differing robustness towards load-shifting events, gradients, and noise. While the SARIMAalgorithm and the linear regression model show extreme error outliers of nRMSE >1, methods viathe LSTM model and the customized statistical approaches perform better with a median nRMSE of0.061 and stable error distribution with a maximum nRMSE of <0.255. The conclusion of this study isa favoring towards the LSTM model and the statistical approach, with regard to MPC applicationswithin photovoltaic-hybrid system solutions in the Ghanaian health sector.
The majority of Niger ’s population faces a widespread lack of access to electricity. Althoughthe country lies in the Sahara belt, exploitation of solar energy is so far minimal. Due to ongoing fossilfuel exploration in the country, this fuel might dominate the future electricity supply. Today, Nigerimports the most of its electricity from Nigeria. There is a need to expand electricity generation andsupply infrastructures in Niger. When doing so, it is important to choose a proper set of electricitygeneration resource/technology that fulfils sustainability criteria. Thus, the objective of this work isto analyze a methodology in order to assess different energy technologies for Niger. A multi-criteriadecision approach was selected to assess the most accessible energy system for the country. Forthis purpose, indicators were developed and weighted for ranking electricity generation options.Altogether 40 indicators are selected under six dimensions (availability, risk, technology, economics,environment and social) to assess eight different alternatives, considering the aggregated results andcorresponding scores under each dimension. A merit list of technology and resources for electricitygeneration presented in this work could support the stakeholders in their decision-making for furtherprojects implementation in the country.
This article explores the relationship between digital transformation and disaster risk.Vulnerability studies aim at differentiating impacts and losses by using fine-grained information fromdemographic, social, and personal characteristics of humans. With ongoing digital development,these characteristics will transform and result in new traits, which need to be identified andintegrated. Digital transformations will produce new social groups, partly human, semi-human,or non-human—some of which already exist, and some which can be foreseen by extrapolating fromrecent developments in the field of brain wearables, robotics, and software engineering. Thoughinvolved in the process of digital transformation, many researchers and practitioners in the field ofDisaster Risk Reduction or Climate Change Adaptation are not yet aware of the repercussions fordisaster and vulnerability assessments. Emerging vulnerabilities are due to a growing dependency ondigital services and tools in the case of a severe emergency or crisis. This article depicts the differentimplications for future theoretical frameworks when identifying novel semi-human groups and theirvulnerabilities to disaster risks. Findings include assumed changes within common indicators of socialvulnerability, new indicators, a typology of humans, and human interrelations with digital extensionsand two different perspectives on these groups and their dependencies with critical infrastructure.
Emergency management services, such as firefighting, rescue teams and ambulances,are all heavily reliant on road networks. However, even for highly industrialised countries such asGermany, and even for large cities, spatial planning tools are lacking for road network interruptionsof emergency services. Moreover, dependencies of emergency management expand not only onroads but on many other systemic interrelations, such as blockages of bridges. The first challenge thispaper addresses is the development of a novel assessment that captures systemic interrelations ofcritical services and their dependencies explicitly designed to the needs of the emergency services.This aligns with a second challenge: capturing system nodes and areas around road networksand their geographical interrelation. System nodes, road links and city areas are integrated into aspatial grid of tessellated hexagons (also referred to as tiles) with geographical information systems.The hexagonal grid is designed to provide a simple map visualisation for emergency planners andfire brigades. Travel time planning is then optimised for accessing city areas in need by weighingimpaired areas of past events based on operational incidents. The model is developed and testedwith official incident data for the city of Cologne, Germany, and will help emergency managers tobetter device planning of resources based on this novel identification method of critical areas.
The Enhancement of standard dense phase carbon dioxide (DPCD) pasteurization by additional mechanical effects wasassessed in this work. These effects were induced during pasteurization by the sudden depressurization in a narrow mini-tube. The high flow velocities, moderate pressures (40–80 bar) and low temperatures (25–45°C) lead to intense degasifica-tion and shear stress. The inactivation of the test microorganismEscherichia coliDH5a(E. coliDH5a) was determinedbefore and after depressurization in the minitube, representing entirely chemical DPCD via dissolved CO2and total inacti-vation comprising the effects of dissolved CO2and mechanical effects, respectively. Compared to conventional DPCDpasteurization, which is mostly attributed to chemical effects, the additional mechanical effects increased the inactivationefficiency considerably.
Enhancing DPCD in Liquid Products by Mechanical Inactivation Effects: Assessment of Feasibility
(2020)
The enhancement of standard dense phase carbon dioxide (DPCD) pasteurization by additional mechanical effects was assessed in this work. These effects were induced during pasteurization by the sudden depressurization in a narrow minitube. The high flow velocities, moderate pressures (40–80 bar) and low temperatures (25–45 °C) lead to intense degasification and shear stress. The inactivation of the test microorganism Escherichia coli DH5α (E. coli DH5α) was determined before and after depressurization in the minitube, representing entirely chemical DPCD via dissolved CO2 and total inactivation comprising the effects of dissolved CO2 and mechanical effects, respectively. Compared to conventional DPCD pasteurization, which is mostly attributed to chemical effects, the additional mechanical effects increased the inactivation efficiency considerably.
Chagas disease is a parasitic infection endemic to America, caused by the protozoan Trypanosoma cruzi and mainly transmitted to humans by contact with insect species of the Triatominae subfamily (Hemiptera). The disease is known to affect disproportionally rural impoverished human communities where it is known to cause premature death and is considered a social and economic burden. The Mexican government has made important progress into the detection, surveillance, treatment, and prevention of the disease in the last decades, however, Chagas disease has also been reported in areas where it had not been previously reported, and there are still barriers for access to treatment. In the state of San Luis Potosi, the disease is more studied in the east, nevertheless, it has been estimated that the reported cases of the entire state have been underestimated. New approaches to detect Chagas risk areas could help prioritize locations for Chagas disease education and prevention programs, detect cases of the disease in a timely manner, and provide access to the necessary treatments. The objective of this study was to identify risk areas for the transmission of Chagas disease in San Luis Potosí using species distribution modelling to estimate vectors and reservoirs’ distributions. To do this, firstly, important vectors and one reservoir species of T. cruzi were identified by reviewing their reported infection rates in literature and the number of times reported in Mexico. Next, species distribution models were calculated for the chosen vector and reservoir species present in the state. The models were done using the Maxent algorithm. Lastly, the resulting distribution models were combined into a risk map by thresholding the model outputs to produce binary predictions and then performing an overlap spatial analysis. Vector species were found to have suitable areas in 36.08% of the state’s territory while areas suitable for both vectors and reservoir were 7.4% of the state’s total area. While this figure may look small at first glance, the analysis suggests that 30% of the rural population and 52% of the urban population of the state are living in an area suitable for vectors and reservoir and therefore at risk. Species distribution modelling can be a powerful tool for identifying human populations at risk of contracting Chagas disease. In the future, including different species of reservoirs into the analysis could help to discover new risk areas in the state.
Wetlands offer different ecosystem services that contribute to human well-being (Kovács et al., 2015). According to the Ramsar Convention Secretariat (2018) wetland located in urban areas have been threatened by several activities such as drainage, pollution, encroachment, agriculture, among others. On the other hand, wetland degradation reduces the resilience of hazards like floods and storm surges (Kumar et al., 2017). For that reason, ecosystem-based disaster risk reduction (Eco-DRR) is an important strategy which enhances the conservation and restoration of ecosystems to reduce disaster risk aiming to sustainable development and resilience (Estrella & Saalismaa, 2013). Despite international recognition of the importance of wetlands, urban wetlands have diminished their capacity to cope with flood threats (Boyer and Polasky, 2006) due to the aforementioned human impacts.
That is why this thesis aimed to identify the role of urban wetlands in Bogota, Colombia, that has an urban wetland complex that is recognised as a Ramsar site in 2018. However, wetlands in the city reduced its area from 50.000 hectares to less than 800, approximately, in less than 40 years, mainly because of urban expansion and encroachment (IDIGER, 2018). To achieve this objective, an analysis of the city’s risk management framework was conducted, as well as a stakeholder analysis based on semi-structured interviews and a spatial-temporal analysis for the period 1998-2017, for which the Jaboque wetland was used as a case study. This wetland is located near the Bogotá River and is in the area threatened by flooding.
It was possible to determine that national and district policies on wetlands, biodiversity, and climate change adaptation address some ecosystem functions. Still, disaster risk reduction is not strongly linked to them. Thus, based on the case study, the wetlands in Bogota have not played a decisive role in flood risk management in the city.
In nahezu jedem Rettungsdienstbereich lässt sich ein Anstieg an Notfalleinsätzen und damit einhergehend ein höherer Bedarf an Rettungsmitteln beobachten. Daraus resultieren Einsatzspitzen, die durch den Regelrettungsdienst nicht abgedeckt werden können, und es entsteht eine Unterdeckung. Dies wird auch als Risikofall bezeichnet und birgt die Gefahr, dass ein Rettungsmittel nicht innerhalb der vorgeschriebenen Hilfsfrist am Notfallort eintreffen kann. Um einen potenziellen Risikofall im Vorfeld absehen und einsatztaktische Ausgleichsmaßnahmen innerhalb eines Rettungsdienstbereiches ergreifen zu können, soll deshalb die Einsatznachfrage in stündlicher Auflösung prognostiziert werden. Dazu wurde die Einsatz-Zeit-Reihe 2017 der hochfrequentierten Feuer- und Rettungswache 1 in der Kölner Innenstadt analysiert und ein saisonales ARIMA-Modell sowie ein Erwartungswert-Modell auf die Einsatz-Zeit-Reihe des Folgejahres 2018 angewandt. Gezeigt werden konnte, dass sich die Einsatz-Zeit-Reihe mit einer mittleren absoluten Abweichung von etwas mehr als einem Einsatz prognostizieren lässt. Außerdem konnte mit einer Skalierung der Prognose über die Anzahl einsatzbereiter Rettungs-wagen jeder Risikofall in einem einwöchigen Anwendungstest vorhergesagt werden. Dabei zeigte sich, dass nicht die Prognosegüte in der Stunde der Einsatzspitze relevant ist, sondern die Prognosegüte in der Folgestunde. Die Prognosen haben somit, wenn sie skaliert werden, eine hohe einsatztaktische Relevanz und ermöglichen kurz-fristige Ausgleichsmaßnahmen im Tagesgang.
Urbanization processes are one of the main factors for habitat loss and fragmentation, driving global biodiversity loss and species extinction. The neotropical Atlantic forest in Brazil is considered a global key biodiversity hotspot and used to be one of the most extensive forests of the Americas. Due to substantial deforestation over centuries, its landscape was transformed into a mosaic of small forest fragments surrounded by a predominantly agricultural matrix. Urban expansion and rural urbanization have created peri-urban zones, which still can harbor natural habitat remnants,
contributing to biological diversity and thus providing essential ecosystem services to urban and rural areas. The maintenance of such ecosystem services requires an understanding of the ecological processes in the ecosystem. A prerequisite for such an in-depth insight is the quantification of the underlying ecosystem functions. The ecosystem function pest control, a trophic interaction between insectivorous birds and herbivorous arthropods, was quantified in an empirical study using artificial caterpillars as prey models. This technique allows the identification of predator groups and the assessment of their predation rates. A total of 888 plasticine caterpillars were distributed at eight sites in secondary forest fragments surrounding the university campus of the federal university of São Carlos (UFScar) in peri-urban Sorocaba, southeastern Brazil. In sixteen point counts, 72 insect-eating birds, belonging to 19 species, were identified as possible artificial caterpillar attackers. Local habitat variables were measured to describe the forest vegetation structure and the landscape context. The study aimed to assess which structural components of the
forest fragments, together with the recorded bird community variables (abundance, richness, αdiversity), best explain the estimated predation rates by birds. The mean predation rate for birds was 8.25 ± 6.3 % for a reference period of eight days, representing the first quantification of the ecosystem function pest control for the study area. The three treatments of caterpillar placement heights (ground, stem: 0.5 -1.0 m, leaf: 1.5 - 2.0 m) were the best and only estimator to explain bird
predation rates. The little dense understory and ground vegetation might have facilitated the accessibility of artificial caterpillars, especially for carnivorous arthropods and birds. The detected contrast in their foraging and predation patterns suggests that arthropods and birds complement each other in their function of pest control. Bird predation rates were found to be negatively related to the vegetation structure. Thus, more open habitats, with less understory and low tree density, but high canopy cover and including dead trees were correlated with the highest predation rates and also exhibited more specialized forest-dependent bird species. This study confirms the importance of the maintenance of forest fragments in peri-urban areas, even if they are small, to preserve forest-associated birds, to contribute to the biological diversity on a broader scale, and to prevent the loss of ecosystem functions and services, mitigating some of the adverse effects of urbanization. Further investigation of the effect among the three treatments of caterpillar
placement on the predation rates is encouraged, including comparative studies among different habitat types. For future studies, it is recommended to model the avian community variables with the vegetation structure measures to predict habitat preferences of insectivorous birds. Therefore, the sampling of more units and on a bigger scale, including over a more extended period, is necessary to improve the robustness of the results, which could provide the basis for a monetary analysis of the ecosystem service pest control by birds.
Habitat loss due to land use and land cover change (LUCC) has been identified as the main cause of global environmental change, responsible for biodiversity decline and the deterioration of ecological processes. Habitat loss and fragmentation have been driven by
processes of LUCC such as deforestation, agricultural expansion and intensification, urbanization, and globalization. The objective of this research was to determine the effects of LUCC on the process of habitat loss and the patterns of fragmentation in the surrounding landscape of the Pacuare Reserve (PR) in the Caribbean lowlands of Costa Rica. The PR is a protected area of 800 ha surrounded by an agricultural landscape with a history of over 150 years of bananas monocultures. Landsat satellite images from 1978 to 2020 were used to conduct a temporal analysis of LUCC around the PR. Patterns of change were explored using landscape metrics from the land classification images. To explore potential connectivity routes, the least cost path analysis was used to connect the PR to other protected areas. Overall, forest cover decreased in the study area at a rate of -4.8% per year during the period of 1992-1997. In the year 2001 it reached its lowest cover and then increased at a mean annual rate of 1.6%. A mean overall accuracy of 92% was obtained for the land classification process. A clear fragmentation process was observed, as shown by a decreased in forest mean patch area and largest patch index and by the increase in patch density. Although forest cover increased in the last decade, fragmentation metrics suggest this recover happened in a spatially scattered manner, due to agricultural land abandonment. Connectivity maps showed the importance of forest fragments and of the already established biological corridors for the movement of species to and from the PR, however it also evidenced the lack of connectivity between the coastal forest fragments and further inside the country located protected areas, as well as the need to promote reforestation projects, particularly between fragments of the corridors identified.
Resilience in relation to flood risk management (FRM) is not a new concept, yet parts of the FRM community are still struggling to apply it. The main challenge this study addresses is the question as to whether parts of the FRM community should still adopt, or rather “leap‐frog,” resilience. The main purpose is to evaluate whether resilience is a still on‐going trend or, already subsiding. Research suggests that resilience is an on‐going trend that connects research and policy and has gained international recognition as expressed by international guidelines and bodies promoting its research but also its operationalization. Academic literature in the area of FRM also shows a significant continuing development. Resilience enables to analyze dynamics and transformations of riverine areas, or coastal zones in connection to an integrated social‐environmental system approach with more emphasis and conceptual basis than previous concepts. Resilience is more than a short‐lived notion and it appears that FRM researchers cannot avoid addressing it. Resilience often is a convergence of ideas and mainstreaming of efforts, which in many venues is absolutely necessary and can help, for example, to decrease silo‐thinking. But as academics, we have a mandate to remain skeptical and remain on the look‐out for novel ideas, too.
This article is categorized under:
Engineering Water > Planning Water
The quantification of greenhouse gas emissions from aquatic ecosystems requires knowledge about the spatial and temporal dynamics of free gas in sediments. Freezing the sediment in situ offers a promising method for obtaining gas‐bearing sediment samples, unaffected by changes in hydrostatic pressure and sample temperature during core withdrawal and subsequent analysis. This article presents a novel freeze coring technique to preserve the in situ stratigraphy and gas bubble characteristics. Nondestructive X‐ray computed tomography (CT) scans were used to identify and characterize coring disturbances of gravity and freeze cores associated with gassy sediment, as well as the effect of the freezing process on the gas bubble characteristics. Real‐time X‐ray CT scans were conducted to visualize the progression of the freezing process. Additional experiments were conducted to determine the freezing rate to assess the probability of sediment particle/bubble migration, and gas bubble nucleation at the phase transition of pore water to ice. The performance of the freeze coring technique was evaluated under field conditions in Olsberg and Urft Reservoir (Germany). The results demonstrate the capability of the freeze coring technique for the preservation of gas‐bearing sediments and the analysis of gas bubble distribution pattern in both reservoirs. Nevertheless, the obtained cores showed that nearly all gravity and freeze cores show some degree of coring disturbances.
Anaerobic digestion plants have the potential to produce biogas on demand to help balance renewable energy production and energy demand by consumers. A proportional integral (PI) controller is constructed and tuned with a novel tuning method to control biogas production in an optimal manner. In this approach, the proportional part of the controller is a function of the feeding rate and system's degree of stability. To estimate the degree of stability, a simulation‐based soft sensor is developed. By means of the PI controller, the requirement for gas storage capacity of the digester is reduced by approximately 30 % compared to a constant, continuous feeding regime of the digester.
Polyimides rank among the most heat-resistant polymers and find application in a variety of fields, including transportation, electronics, and membrane technology. The aim of this work is to study the structural, thermal, mechanical, and gas permeation properties of polyimide based nanocomposite membranes in flat sheet configuration. For this purpose, numerous advanced techniques such as atomic force microscopy (AFM), SEM, TEM, TGA, FT-IR, tensile strength, elongation test, and gas permeability measurements were carried out. In particular, BTDA–TDI/MDI (P84) co-polyimide was used as the matrix of the studied membranes, whereas multi-wall carbon nanotubes were employed as filler material at concentrations of up to 5 wt.% All studied films were prepared by the dry-cast process resulting in non-porous films of about 30–50 μm of thickness. An optimum filler concentration of 2 wt.% was estimated. At this concentration, both thermal and mechanical properties of the prepared membranes were improved, and the highest gas permeability values were also obtained. Finally, gas permeability experiments were carried out at 25, 50, and 100 ◦C with seven different pure gases. The results revealed that the uniform carbon nanotubes dispersion lead to enhanced gas permeation properties.
Water risk assessment is becoming an essential part of any decision-making process in the business sector. In the world where freshwater resources are becoming scarcer, water risks are growing and causing high costs to businesses. Therefore, numerous frameworks, guidelines, methodologies, tools, and other approaches were developed during the last century. Various scholars have appeared to give an economic value or price for environment goods in order to understand trade-offs better. Nowadays, the corporate world tends to use different approaches to convert sustainability management data to the financial language of decision-makers. This study explores the possible ways for a company to measure the costs of water related risks. It examines how to convert water risks to financial risks using a Peruvian agricultural company. The results show, that from all today’s available frameworks, guidelines or tools there is no one commonly accepted and recognised as the best for water risk assessment and monetising. It was learned, that available tools could provide just a simple overview of possible water related risks and calculate their costs in a very general way. The work also highlights the importance of regular and appropriate data collection on the company level in order to be able to assess water risk related costs for the business.
Durch das permanente Wachstum der Weltbevölkerung wird der Bedarf von Textilien stetig steigen. Die Produktvielfalt sowie der Konsum der Textilien werden immer größer. Die aktuellen Recyclingtechniken ermöglichen es nicht, den Rohstoffkreislauf für Textilien zu schließen. Dies liegt auch darin begründet, dass derzeit große Mengen der Textilien aus Mischgeweben zwischen Baumwolle und PET bestehen. Die Trennung dieser Komponenten ist jedoch eine Grundvoraussetzung für die Entwicklung eines geschlossenen Rohstoffkreislaufs und stellt gleichzeitig eine große Herausforderung für das Recycling dar. Durch chemische Recyclingverfahren können die Rohstoffe getrennt, aufbereitet und in die Textilproduktion zurückgeführt werden. In dieser Arbeit wird aufgezeigt, wie ein chemischer Recyclingprozess, der einen geschlossenen Rohstoffkreislauf erlaubt, technisch realisiert werden kann. Der Prozess erzeugt eine PET-Fraktion und eine Celluloselösung, die in weiteren Verarbeitungsschritten zu einer Regeneratfaser versponnen wird. In dieser frühen Projektphase werden in dieser Arbeit ebenfalls die Investitionsausgaben und die Herstellungskosten für das Verfahren abgeschätzt.
Die vorliegende Masterarbeit behandelt die Bewertung der eingegangenen Unternehmensrisiken im Rahmen der Lebensversicherung und die hiervon abgeleiteten Auswirkungen zur Unternehmenssteuerung.
Dabei wird einerseits die Angemessenheit der sog. „Standardformel“ nach Solvency II überprüft, die in den europäischen Mitgliedsstaaten einen weitestgehend einheitlichen Ansatz bei der Bewertung der Risiken von Versicherungsunternehmen verwendet. Andererseits werden unter ökonomischen Überlegungen versicherungsmathematische Methoden vorgestellt, wie ein Lebensversicherer seine Risiken unternehmensindividueller ermitteln und damit seinen tatsächlichen Risikokapitalbedarf bestimmen kann.
Zur Quantifizierung der Ergebnisse werden die Berechnungsvorgaben der Standardformel für ausgewählte Risikomodule nachgebildet und mit den in dieser Arbeit vorgestellten unternehmensindividuellen Berechnungen verglichen und analysiert. Es zeigt sich, dass trotz der Komplexität des Solvency II-Modells eine noch differenziertere Herangehensweise notwendig ist, damit ein einzelnes Unternehmen seine Risiken adäquat und möglichst individuell bestimmen kann. Zur Gewährleistung einer nicht bestandsgefährdenden Unternehmensfortführung müssen die Versicherungsunternehmen bei Betrachtung ihrer Risiken mithilfe des EU-weiten Aufsichtssystems Solvency II in der Lage sein, die korrekten Rückschlüsse zur Unternehmenssteuerung zu ziehen. Die in dieser Arbeit vorgestellten versicherungsmathematischen Ansätze können dabei den Prozess zur unternehmenseigenen Risiko- und Solvabilitätsbeurteilung (ORSA) unterstützen.
The post-conflict setting in Colombia resulted after the signing of the peace agreement between the Revolutionary Armed Forces of Colombia (FARC) and the national Government at the end of 2016, faces two main problems. On one hand, the environmental degradation and the pressure over the ecosystems now exposed to the economic and socio-demographic dynamics of the country; and on the other hand, the increase of violence in rural areas characterized by the abundance of natural resources. These two problems can be linked through the complex dynamics of natural resources appropriation. Among the natural resources affecting the course of the post-conflict in Colombia, gold appears as one of the most relevant sources of violence and environmental degradation. This condition makes it crucial to understand the complex local dynamics of mining regions in order to propose alternatives for consolidating a sustaining peace. The armed groups, the state, the private companies, and traditional gold mining communities are all stakeholders involved in gold mining and the conflicts around this activity. Nevertheless, communities have been denied as a formal actor.
This work aims to give voice to those communities, understanding them as a key actor for peacebuilding. This research seeks to understand the relationship between gold mining and the social-armed conflict in Colombia, to identify which are the drivers for the increasing of this activity during the post-conflict, as well as which strategies developed by traditional gold mining communities can contribute to peacebuilding. Thus, an integrative analytical framework is developed. This theoretical framework integrates 1) environmental peacebuilding to evaluate the possibilities of natural resources to becoming tools for cooperation, and 2) political ecology to clarify, from a multi-scalar approach, the socio-political context in which the conflict takes place. Hence, from a qualitative approach that involves several ethnographic methods is found that artisanal-ancestral miners and traditional miners organized to remain in their territories in a context of dispossession, have developed socio-ecological systems and natural resources management strategies relevant to implement initiatives of environmental peacebuilding that can be sustained over time and aimed to overcome the structural causes of violence and environmental degradation.
STEPsCON 2018 was jointly organized by the Faculty of Applied Natural Sciences of TH Köln (Germany) and the University of Oulu (Finland) on the occasion of the 50th anniversary of the Leverkusen – Oulu town twinning. The conference focused on sustainability issues and covered the current state of research in four key topics:
1. Sustainable Medicine and Pharmaceuticals
2. Resources and Bioremediation
3. Sustainable Chemistry & Industrial Biotechnology
4. Innovative Materials & Formulations
For use in a landfill, a laboratory reactor for safe and environmentally friendly biological utilization of low-concentration methane gas will be further developed. The current principle of denitrification-coupled aerobic methane oxidation will be replaced by methane oxidation under anaerobic conditions. Anaerobic methane oxidation offers the advantage that, in addition to methane, nitrate also undergoes biodegradation. Another advantage is that the oxygen content can be significantly lower. This reduces the risk of the formation of an explosive atmosphere in the reactor. Currently, the principle of anaerobic methane oxidation is known. However, organisms capable of doing so are not yet available as a pure culture. Therefore, several biomasses were probed for the ability of anaerobic methane oxidation. It was found that moor-heavy sediment, activated sludge from the leachate treatment plant and biomass from the local biogas plant oxidize methane after the natural carbon source (C source) was been removed.
The synthesis of 17-hydroxy-oleic acid based oligomeric esters was investigated with immobilized Pseudozyma antarctica Lipase B and hexanediol as co-substrate. The effects of different reaction parameters on velocity and product composition at equilibrium conditions were analyzed. The synthesis of oleic acid esters was used as a reference system for initial evaluation of reaction parameters. The reaction with oleic acid and hexanediol was fastest at an enzyme concentration of 5% at 60 °C and high conversions of > 90 % were achieved in non-polar solvents in the presence of molecular sieves. In heptane an oleic acid conversion of 96 % was reached with a final diester to monoester ratio of > 4:1. In syntheses trials with 17-hydroxy-oleic acid the formation of oligomers was verified with GPC, however; conversion was generally lower than with oleic acid. Removal of hydroxyl fatty acid monomers and dimers and the formation ester functionalities could be verified by GC analysis. An increase of the degree of oligomerization was observed simultaneously by GPC analysis. The number-average molecular weight was around 1400 in the best trials corresponding to a degree of oligomerization of around 4 units of hydroxyl-fatty acid attached to a hexanediol core. Though transformations were not complete, the final oligomer size was in the lower range of polyester diols used for polyurethane manufacturing.
Due to the worldwide shortage of petrochemical based resources, the usage of renewable bio-based raw materials for established and novel products becomes increasingly important.[1] Such bio-based resources are already used for the fabrication of a variety of products, e. g. paper, lubricants, detergents or cosmetics. In the future they are expected to emerge in many more applications in industry and household.[1]
A very promising approach relies on the use of glycolipids as a source of hydroxy-oleic acid.[2] Microbial glycolipids are produced for instance via fermentation from natural resources such as plant oils and sugar.[3] After fermentation complex product mixtures are obtained with the composition depending on the microorganism, substrate and fermentation time.[3] The successful use of microbial glycolipids and hydroxy-oleic acid (HOA) derived therefrom as bio-based intermediates requires reliable analytical methods as well as robust manufacturing processes for the synthesis and cleavage of bio-based molecules. In order to obtain hydroxy-oleic acids as bio-based intermediates, the acidic cleavage of microbial derived sophorolipid was investigated. In addition the implementation of HOA in polyurethane (PU) systems was explored.
The introduction of Feed-in tariffs in the German Renewable Energy Act (EEG) fuelled the growth of anaerobic digestion (AD) industry making Germany the country with highest number of operational AD plants. However, the rapid expansion of AD industry resulted in some unwanted side-effects such as food vs fuel debate, increased prices for electricity and the temporal mismatch between supply and demand of electricity grid. Subsequent amendments in EEG has tried to address some of these issues by reduction in Feed-in tariffs, introduction of a cap on cereal based feedstocks and providing premium for energy production in accordance with market demand. Furthermore, the Feed-in tariffs which were introduced for 20 years are soon going to expire. The changes in legal and political discourse is soon going to introduce some new challanges to the AD industry. This paper has discussed some of these challanges and their potential solutions.
The electricity network is undergoing a change due to reducing costs for renewable energy sources. Subsidy programs for renewable energy sources are changing and the funding available is being reduced. This will have an impact on anaerobic digestion which in some cases may struggle financially. Overfeeding is one of the most common mechanisms of inhibition in the process, and by shifting to intermittent feeding for on-demand production, this change will provide more information about the digestion process and could be used to detect the beginning of inhibition due to overfeeding. This paper discusses the shift towards intermittent production and how this change can be used to monitor the anaerobic digestion process.
Comparative analysis of non-natural acceptor glucosylation with sucrase enzymes of family GH 70
(2019)
Mutan- and alternansucrase were analyzed for their non-natural glucosylation potential with catecholic compounds caffeic acid and nordihydroguaiaretic acid (NDGA) as well as with non-catecolic p-coumaric acid and umbellic acid. Mutansucrase accepted both catecholic substrates and high glucosylation yields of 92 % with caffeic acid and 81 % with NDGA were obtained. The enzyme showed a clear regio-preference for the catechol 4-OH, which corresponds to findings from our previous work with Leuconostoc and Weissella derived glucansucrases. The substrate spectrum of the alternansucrase was broader and all substrates were successfully glucosylated with a preference for the catechols. Interestingly alternansucrase possessed a different regio-specificity. With caffeic acid the 3-O-α-D-glucoside was the major product. A similar substrate spectrum and regioselectivity pattern was observed in previous glucansucrase screenings only with glucansucrase from strain Weissella beninensis DSM 22752. Therefore it may be concluded that the W. beninensis enzyme is an alternansucrase type enzyme as well.
In the degradation of ammonia (NH4+) to gaseous nitrogen (N2), the nitrification is one of the two reaction steps. The nitrification itself is divided in two steps and is performed by two different types of bacteria. Current literature has shown that there are types of bacteria, which have the genetic equipment to perform both steps in one bacteria. Nevertheless, in wastewater and landfill leachate treatment, ammonia-oxidizing organisms (AOO) and nitrite-oxidizing organisms (NOO) occur as a symbiosis. The intermediate of the two consecutive reaction steps (NO2-, nitrite) is toxic. For this reason, both steps are necessary for the two bacterial groups. To determine the ratio of AOO, NOO and heterotrophic bacteria (which use organic compounds as carbon and energy source) the oxygen uptake rate (OUR) with selective inhibition with N-allylthiourea (ATU) and azide is used. In the inflow of a pilot plant in one street a step by step increased amount of a process water out of a fermentation plant was added to the landfill leachate. For comparison, the other street was supplied only with landfill leachate with the same amount of nitrogen. As a result, comparable values for the different bacterial groups and reproducible results were measured and lead to a better understanding of the analysed nitrification sludge. Deeper understanding of the behavior of the different groups will result in a reduce risk of malfunctions and a more stable operation in the wastewater or landfill leachate treatment plant.
The whole site of the waste disposal centre Leppe in Lindlar has been modified by the project :metabolon into an authentic learning site for knowledge transfer. Addressing all age groups, the project offers insights into environmental knowledge and explains contexts of resources and material flows. The site conditions allow practical outlooks on future energy systems. Following the meta theme of “lifetime learning”, pupils and students are addressed by different modules, considering their individual learning levels.
Aerobic microbial cultivations are industrially important group of processes and pose challenges for the reactor design. In particular, estimation of industrial scale conditions is difficult from laboratory and pilot scale data. Due to complex interaction of gas/liquid phase hydrodynamics, mass transfer parameters and microbial metabolism, both improvement of modelling tools and reactor design are desired. We present an approach to estimate growth conditions in industrial scale reactor by combining black-box metabolic models with CFD-model.
The reactor type used here is Outotec OKTOP9000®, which is used in the industrial hydrometallurgical processes at 900 m3 scale. It is adopted to a laboratory setting and compared to stirred tank reactor (STR) in gas dispersion, mass transfer and yeast cultivation experiments. In addition, a kinetic model for the yeast growth is developed based on literature sources and validated by the laboratory scale batch cultivations. This kinetic model is used along with CFD-model that is developed to describe the flow and mass transfer conditions in the industrial scale reactor.
The laboratory scale experiments show the feasibility of OKTOP9000® reactor when compared to STR, particularly with improved gas handling capacity. The modelling approach shows qualitatively similar behavior in the large scale simulations when compared to laboratory scale cultivations.
Before transporting the landfill leachate to municipal wastewater treatment plant it has to be treated in a landfill leachate treatment plant, as it comprises high concentrations of ammonium. The elimination of ammonium load in the leachate is usually done by the combined processes of nitrification and denitrification with a specially adapted biocenosis in the activated sludge (AS). For each of the steps, specialized bacteria such as Nitrosomonas, Nitrobacter and Paracoccus are used to transfer the ammonia to gaseous nitrogen. The aim of this investigation was to find suitable process parameters for a complementary treatment of fermentation water from a biogas plant together with landfill leachate. The processed water of the biogas plant consists of a higher concentration of ammonium and carbon sources or easily degradable volatile fatty acids. It can save the usage of external carbon source (acetic acid) and additionally it could also compensate the missing volumes of leachate in times of low rain and low leachate flows. To maintain the high workload for the existing leachate treatment pilot plant (LTPP), a combined treatment of landfill leachate and process water is also of economic and of ecological interest. The long-term adaption process of the biocenosis needs to be done step-by-step. Innovative process monitoring is needed to prevent biocenosis collapse. In our study, we present our set-up, a closer look at the ongoing experiment and the long-term changes in the biocenosis.