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Untersuchung der Yosys Hardwaresynthese von der internen Datenstruktur RTLIL bis zur Netzliste
(2023)
Das Ziel dieser Arbeit ist die Beantwortung der Frage "Wie funktioniert Synthese?". Yosys ist ein offenes Synthesewerkzeug, welches untersucht wurde, um diese Frage zu beantworten. Yosys implementiert eine Datenstruktur RTLIL, mit der ein Entwurf in allen Synthesephasen dargestellt wird. Yosys ist modular aufgebaut, was dem Nutzer ermöglicht, das Programm zu erweitern. Die Synthese in Yosys ist auf Pässe unterteilt, die jeweils eine bestimmte Aufgabe erfüllen. Im Rahmen der Arbeit wurde die Datenstruktur und die Passes im einzelnen analysiert. Es wurde auch untersucht, wie in Yosys Erweiterungen zu implementieren sind. Die Analyse hat gezeigt, dass ein wichtiger Teil der Synthese die Umwandlung von Prozessen in eine RTL-Beschreibung darstellt. Im Rahmen der Synthese werden die, von einem Frontend vorläufig erzeugten RTL-Komponenten, umgewandelt. Der letzte Schritt der Synthese ist das Technologiemapping, welches die umgewandelten Komponente auf die verwendete Hardware anpasst.
Cloud Computing ist der zentrale Faktor zur Beschleunigung der Digitalisierung in Deutschland und wird in den kommenden Jahren eine wichtige Rolle in jedem deutschen Unternehmen spielen. Für Unternehmen wird es dabei um die Umsetzung von
Cloud-Strategien und die praktische Einbindung in die täglichen Betriebsprozesse gehen. Zusätzlich müssen Unternehmen ihre bestehende Datenlandschaft in moderne Architekturen zum Datenmanagement in die Cloud migrieren. Dabei können Unternehmen auf eine Vielzahl an unterschiedlichen unternehmensweiten Datenarchitekturen
zurückgreifen. Die vorliegende Masterarbeit gibt eine Einführung in die aktuelle Entwicklung von Cloud Computing und erläutert, mit Data Fabric, Data Lakehouse und Data Mesh, drei unternehmensweite Datenarchitekturen für die Cloud. Data Fabric, Data Lakehouse und Data Mesh bilden dabei aktuell die modernsten Konzepte für unternehmensweite Datenarchitekturen. Zusätzlich werden ein Data Lakehouse und ein Data Mesh in einer ausgewählten Cloud-Umgebungen entworfen, prototypisch aufgebaut und praktisch analysiert. Ziel der Masterarbeit ist es, die unternehmensweiten Datenarchitekturen in der Cloud zu erläutern, konkrete technologische Architekturen zu entwerfen und entsprechende Hinweise zu Aufwandstreibern in Unternehmen zu identifizieren.
Decisions on irrigation water management are usually made at different levels, including farms, water user associations (WUAs), and regional water planning agencies. The latter generally have good access to information and decision tools regarding water resources management. However, these remain out of reach to the final water users, namely the farmers. The study, conducted in the irrigated district of Cherfech, north Tunisia, had the main objective of investigating farmer’s perceptions of, and acceptance for, the use of an irrigation advisory service (IAS) to be implemented by their WUA. The suggested IAS provides the following information: (1) reference evapotranspiration (ETo) and rainfall; (2) crop water requirement (CWR) of the most cultivated crops; (3) irrigation water requirement (IWR) of the farmer’s crop; and (4) crop monitoring and real-time estimation of IWR of crops settled, using soil moisture sensors. Such services and information would be available at the WUA level and provided in a timely manner to farmers for more effective decision making at the plot level. Prior to the acceptance study, we launched a technical study to determine the required tools and equipment required for the implementation of the IAS, followed by a farmer survey to assess their respective perceptions and acceptance towards this IAS. Results showed that only 54% of the farmers are satisfied by WUAs work, but that 77% of them accepted using the suggested IAS. Farmers are also willing to pay for most of the IAS packages suggested. The financial profitability of investing in the IAS at the WUA level shows the venture is financially viable, with a benefit cost ratio (BCR) of 1.018. The project will be even more profitable if we add the social benefits, which may result in water savings at the WUA level.
The importance of lithium as a raw material is steadily increasing, especially in the growing markets of grid energy and e-mobility. Today, brines are the most important lithium sources. The rising lithium demand raises concerns over the expandability and the environmental impact of common mining techniques, which are mainly based on the evaporation of brine solutions (Salars) in arid and semiarid areas. In this case, much of the water contained in the brine is lost. Purification processes lead to further water losses of the ecosystems. This calls for new and improved processes for lithium production; one of them is electrodialysis (ED). Electrodialysis offers great potential in accessing lithium from brines in a more environmentally friendly way; furthermore, for the recovery of lithium from spent lithium-ion batteries (LIB), electrodialysis may become a vital technology. The following study focused on investigating the effect of varying brine compositions, different ED operation modes, and limiting factors on the use of ED for concentrating lithium-containing brine solutions. Synthetic lithium salt solutions (LiCl, LiOH) were concentrated using conventional ED in batch-wise operation. While the diluate solution was exchanged once a defined minimum concentration was reached, the concentrate solution was concentrated to the respective maximum. The experiments were conducted using a lab-scale ED-plant (BED1-3 from PCCell GmbH, Germany). The ion-exchange membranes used were PCSK and PCSA. The treated solutions varied in concentration and composition. Parameters such as current density, current efficiency, and energy requirements were evaluated. ED proved highly effective in the concentration of lithium salt solutions. Lithium chloride solutions were concentrated up to approximately 18-fold of the initial concentration. Current efficiencies and current densities depended on voltage, concentration, and the composition of the brine. Overall, the current efficiencies reached maximum values of around 70%. Furthermore, the experiments revealed a water transport of about 0.05 to 0.075% per gram of LiCl transferred from the diluate solution to the concentrate solution.
Porous polymer membranes substantially contribute to an acceleration of sustainability transformation based on the energy efficient separation of liquid and gaseous mixtures. This rapid shift toward sustainable industrial processes leads to an increased demand for specifically tailored membranes. In order to predict membrane performance factors like permeability, selectivity and durability, the membrane formation process by film casting and phase inversion needs to be understood further. In recent years, computational models of the membrane formation process have been studied intensely. Their high spatial and temporal resolution allows a detailed quantitative description of phase inversion phenomena. New experimental techniques complement this development, as they provide quantitative data, e.g., on compositional changes of the polymer solution during membrane formation as well as the kinetic progression of the phase separation process. This state-of-the-art review compiles computational and experimental approaches that characterize the phase inversion process. We discuss how this methodological pluralism is necessary for improving the tailoring of membrane parameters, but that it is unlikely to be the way to the ultimate goal of a complete description of the evolution of the membrane structure from the initial demixing to the final solidification. Alternatively, we formulate an approach that includes a database of standardized and harmonized membrane performance data based on previously publicized data, as well as the application of artificial neural networks as a new powerful tool to link membrane production parameters to membrane performance.
Agents with antifungal activity play a vital role as therapeutics in health care, as do fungicides in agriculture. Effectiveness, toxicological profile, and eco-friendliness are among the properties used to select suitable substances. Furthermore, a steady supply of new agents with different modes of action is required to counter the well-known potential of human and phyto-pathogenic fungi to develop resistance against established antifungals. Here, we use an in vitro growth assay to investigate the activity of the calcineurin inhibitor tacrolimus in combination with the commercial fungicides cyproconazole and hymexazol, as well as with two earlier reported novel {2-(3-R-1H-1,2,4-triazol-5-yl)phenyl}amines, against the fungi Aspergillus niger, Colletotrichum higginsianum, Fusarium oxysporum and the oomycete Phytophthora infestans, which are notoriously harmful in agriculture. When tacrolimus was added in a concentration range from 0.25 to 25 mg/L to the tested antifungals (at a fixed concentration of 25 or 50 mg/L), the inhibitory activities were distinctly enhanced. Molecular docking calculations revealed triazole derivative 5, (2-(3-adamantan-1-yl)-1H-1,2,4-triazol-5-yl)-4-chloroaniline), as a potent inhibitor of chitin deacetylases (CDA) of Aspergillus nidulans and A. niger (AnCDA and AngCDA, respectively), which was stronger than the previously reported polyoxorin D, J075-4187, and chitotriose. The results are discussed in the context of potential synergism and molecular mode of action.
Hydroxybenzene, commonly known as phenol, is one of the most important organic commodity chemicals. To produce phenol, the cumene process is the most used process worldwide. A crucial step in this process is the Hock rearrangement, which has a major impact on the overall cumene consumption rate and determines the safety level of the process. The most used catalyst for the cleavage of cumene hydroperoxide (CHP) is sulfuric acid. Besides its strong corrosive property, which increases plant investment costs, it also requires neutralization after the decomposition step to prevent side reactions. In this study, we show that high-temperature-treated Linde Type X (LTX) zeolites exhibit a high activity for the peroxide cleavage step. In addition, the structure–activity relationship responsible for this good performance in the reaction system of the HOCK rearrangement was investigated. XRPD analyses revealed the formation of a new phase after temperature treatment above 900 °C. The Si/Al ratio determined by EDX suggested the formation of extra-framework aluminum, which was confirmed by solid-state NMR analysis. The newly formed extra-framework aluminum was found to be responsible for the high catalytic activity. BET analyses showed that the surface area drops at higher calcination temperatures. This leads to a lower catalytic activity for most known reactions. However, for this study, no decrease in activity has been observed. The newfound material shows extraordinarily high activity as a catalyst in the HOCK cleavage and has the potential to be a heterogeneous alternative to sulfuric acid for this reaction.
In recent years, three sovereign catastrophe risk pools have developed worldwide, offering climate insurance against natural disasters in emerging and developing economies:
• Caribbean Catastrophe Risk Insurance Facility (CCRIF) in the Caribbean
• African Risk Capacity (ARC) in Africa
• Pacific Catastrophe Risk Insurance Company (PCRIC) in the Pacific region
These pools have emerged against the backdrop of limited fiscal room for manoeuvre in emerging and developing economies. Increases in tax revenues or capital allocations are scarcely possible in these economies. Moreover, debt on the capital market often ends in debt relief, and this can jeopardise refinancing. Ultimately, the only measure remaining is to provide donations and aid that can be made available by the G7 countries, the World Bank or the World Health Organization, among others.
In den letzten Jahren haben sich weltweit drei Sovereign Catastrophe Risk Pools entwickelt, welche Klimaversicherungen gegen Naturkatastrophen in Schwellen- und Entwicklungsländern anbieten:
• Caribbean Catastrophe Risk Insurance Facility (CCRIF) in der Karibik
• African Risk Capacity (ARC) in Afrika
• Pacific Catastrophe Risk Insurance Company (PCRIC) im pazifischen Raum
Hintergrund für die Entwicklung dieser Pools ist der geringe fiskalpolitische Spielraum in Schwellen- und Entwicklungsländern. So sind Erhöhungen von Steuereinnahmen oder Kapitalallokationen kaum möglich. Außerdem endet eine
Verschuldung am Kapitalmarkt häufig im Schuldenerlass, wodurch eine Refinanzierung gefährdet werden kann. Schließlich bleiben nur noch Spenden und Hilfsgelder als Maßnahme übrig, welche u.a. durch die G7-Staaten, die Weltbank oder die Weltgesundheitsorganisation zur Verfügung gestellt werden können.
Today, IT infrastructure represents the central nervous system of every company. Many of the activities of our daily lives are handled via the Internet. There is a lack of an adequately sustainable awareness of the cyber risks to which companies are exposed due to advanced digital networking. This is partly due to the fact that the danger of so-called ‘cyber attacks’ is only partially palpable to many, with attacks going unnoticed in some cases. As a result of major incidents, such as WannaCry and Petya in 2017, or Emotet in 2019, awareness of these risks should be keen, and yet vulnerability remains high due to the often insufficient protections against cyber crime.