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Der vorliegende Bericht ist ein ökonomischer Vergleich
verschiedener Varianten der Überschussschlamm
(ÜSS)-Verwertung der Sickerwasseranlage
auf der Deponie des Entsorgungszentrums Leppe
mit dem aktuellen Entsorgungsweg. Als Vergleichsparameter
werden die Jahresvollkosten herangezogen.
Der derzeitige Entsorgungsweg über die kommunale
Kläranlage wird hierbei als Basisvariante
betrachtet und mit alternativen Behandlungs- und
Verwertungsmöglichkeiten verglichen. Hierbei werden
verschiedene Varianten mit unterschiedlichen
Ausführungen der Komponenten Lagerung, Entwässerung,
Trocknung, Transport und Verbrennung
gegenübergestellt.
The introduction of Feed-in tariffs in the German Renewable Energy Act (EEG) fuelled the growth of anaerobic digestion (AD) industry making Germany the country with highest number of operational AD plants. However, the rapid expansion of AD industry resulted in some unwanted side-effects such as food vs fuel debate, increased prices for electricity and the temporal mismatch between supply and demand of electricity grid. Subsequent amendments in EEG has tried to address some of these issues by reduction in Feed-in tariffs, introduction of a cap on cereal based feedstocks and providing premium for energy production in accordance with market demand. Furthermore, the Feed-in tariffs which were introduced for 20 years are soon going to expire. The changes in legal and political discourse is soon going to introduce some new challanges to the AD industry. This paper has discussed some of these challanges and their potential solutions.
Mit Hilfe der Inline-ATR-FTIR-Spektroskopie im mittelinfraroten (MIR) Spektralbereich lassen sich gleich mehrere Prozessparameter für Biogasanlagen in Echtzeit und ohne Probenahme verfolgen. Die gemessenen Absorptionsspektren geben simultan Aufschluss über den Gehalt an flüchtigen organischen Säuren (FOS), die alkalische Pufferkapazität (TAC) und die Ammoniumstickstoff-Konzentration (NH4-N).
Dabei können unter Verwendung intelligenter Datenanalyseverfahren, wie z.B. Partial Least Squares (PLS), Regression oder Support Vector Regression (SVR) sowie in kontrollierter Laborumgebung, Vorhersagefehler (RMSECV) von 0.372 g/l (FOS: R2=0.971), 0.336 g/l (TAC: R2=0.996) und 0.171 g/l (NH4-N: R2=0.992) im Falle der PLS, bzw. 0.386, 0.259 und 0.110 g/l für die SVR erreicht werden.
Erste Inline-Messungen in einer Biomüllvergärungsanlage zeigen, dass die erwarteten Absorptionsbanden auch im Prozessbetrieb wiedergefunden werden können. Sie unterliegen jedoch einem ausgeprägten Temperatureinfluss, der bei der Quantifizierung dieser Prozessdaten berücksichtigt werden muss. Weiterführende Untersuchungen sind notwendig, um die Inline-Tauglichkeit des Messsystems unter Beweis zu stellen.
Die Messung des Chemischen Sauerstoffbedarfs (CSB) im Zulauf von Kläranlagen ist von zentraler Bedeutung für die Optimierung und Regelung der Abbauprozesse der Nitrifikation und Denitrifikation. Allerdings ist die Messung des CSB bislang sehr zeitaufwändig und kostenintensiv, da 24-Stunden Mischproben im Labor nasschemisch analysiert werden müssen.
Online-Messtechnik in Form von spektroskopischen Messgeräten (10.000 ̶ 20.000 €) oder nass-chemischen Online-Analysatoren (> = 50.000 €) sind insbesondere für kleine und mittlere Kläranlagen aus Kostengründen keine Alternative.
Eine extrem kostengünstige Alternative ist der im Folgenden beschriebene Softsensor für CSB im Kläranlagenzulauf, der auf Basis von Standardmesstechnik im Zulauf von kleinen und mittleren kommunalen Kläranlagen sowie mit zusätzlicher Online-Messtechnik für Trübung sowie Ammonium- und Nitratstickstoff (NH4-N und NO3-N) die aktuelle CSB-Konzentration bestimmt. Zur Entwicklung des Softsensors werden Regressionsmethoden aus dem Bereich des Machine Learning eingesetzt. Die Ergebnisse einer Entwicklungs- und Testphase an der Kläranlage Rospe in Gummersbach zeigen, dass die Werte des Softsensors sehr gut mit den Originaldaten übereinstimmen. Die Korrelationswerte beim Vergleich mit CSB-Messungen liegen bei der Regression mit Support Vector Regression bei 0,98 mit einem RSME von 2,45 mg/l.
Pseudozyma antarctica Lipase B catalyzed esterification and transesterification in deep eutectic solvents (DES) was investigated in reaction systems with alcohols of different polarity. Coconut oil and crude biodiesel were deacidified successfully with non-immobilized CALBL and final acid values of 1.2 for biodiesel and 0.5 for coconut oil were obtained, while no esterification with ethanol was observed without DES. Water depletion of the lipid phase in the presence of water adsorbing DES causes this difference. Analysis of water contents revealed a 10 fold lower water content of the lipid phase in the presence of a second DES phase than in trials without utilization of DES. In contrast reactions of hydrophilic polyols are suppressed in the presence of DES. While the esterification of fructose and the transesterification with glycerol worked well in the polar solvent 2-methyl-2-butanol, almost no fructose esterification and a decreased transesterification with glycerol were observed in the presence of DES. Analysis of logP values of the substrates explains the substrate dependent differences in reactivity. The polar alcohols are probably bound strongly in the hydrogen-bonding network of the DES phase and are thus not available for lipase catalyzed reactions.
In the last few decades raw material molasses, used in large scale fermentations in the production of bioethanol, citric acid, (baker´s) yeast and yeast extracts, has become more and more expensive. That is why agro-industrial wastes have become an interesting alternative. They are being produced in large volumes every day and represent a serious environmental problem considering its high organic content. The present contribution aims to demonstrate how waste products of wine production can be employed as substrate in bioethanol production. Cultivation of yeast and bioethanol production on molasses and grape pomace extract was studied in flasks in laboratory scale. This work should be regarded as an example of integrated sustainability which demonstrates how the waste from one industrial process is used as feedstock for another.
The utilization of roadside-green-cuttings (grass) for anaerobic digestion increases provides an additional possible source of organic waste for use as a renewable energy source. Grass can be used as a substrate to increase biogas yield. Nevertheless, the anaerobic digestion of this kind of waste can be limited due to the fact that it could be contaminated with heavy metals, in particular from traffic emissions and industrial activity. For this reason the biogas production of grass from a busy road was assessed. Samples of roadside-grass were washed with an organosulphide, which is used for the removal of heavy metals from wastewater.
A comparison of the anaerobic digestion of washed and unwashed roadside grass was performed. Results showed that the anaerobic digestion of the unwashed grass was much more effective than the washed grass. A second experiment was carried out and co-fermentation of manure and farm-grass was prepared for anaerobic digestion. Lead was added in the concentrations 500, 1000 and 2000 mg Pb2+/kg. The results showed that the higher the lead concentration, the lower the inhibition of the biogas yield. The grass could be acting as phytoremediator for high lead concentrations. The grass could contain organic compounds, which can as-similate heavy metals.
Biogas, mit geringen Konzentrationen an Methan, entsteht unter anderem bei verschiedenen industriellen Prozessen. Wegen der Umweltschädlichkeit des Methans gilt es dessen Eintrag in die Umwelt zu vermeiden.
Das Ziel des vorgestellten Projektes war die Überprüfung eines umweltfreundlichen Verfahrens zur Reduzierung des Methans durch methanotrophe Bakterien. Die einzelnen Batchversuche liefen über 15 Stunden und zeigten eine starke Reduzierung des Methans von 18 auf 1 Vol.-%.
Comparative analysis of non-natural acceptor glucosylation with sucrase enzymes of family GH 70
(2019)
Mutan- and alternansucrase were analyzed for their non-natural glucosylation potential with catecholic compounds caffeic acid and nordihydroguaiaretic acid (NDGA) as well as with non-catecolic p-coumaric acid and umbellic acid. Mutansucrase accepted both catecholic substrates and high glucosylation yields of 92 % with caffeic acid and 81 % with NDGA were obtained. The enzyme showed a clear regio-preference for the catechol 4-OH, which corresponds to findings from our previous work with Leuconostoc and Weissella derived glucansucrases. The substrate spectrum of the alternansucrase was broader and all substrates were successfully glucosylated with a preference for the catechols. Interestingly alternansucrase possessed a different regio-specificity. With caffeic acid the 3-O-α-D-glucoside was the major product. A similar substrate spectrum and regioselectivity pattern was observed in previous glucansucrase screenings only with glucansucrase from strain Weissella beninensis DSM 22752. Therefore it may be concluded that the W. beninensis enzyme is an alternansucrase type enzyme as well.
This paper presents a series of flow and temperature measurements on the principal heat network of :metabolon in Lindlar, Germany. These measurements intend to show the behaviour of the system on specific production areas of :metabolon for future monitoring and optimisation purposes. Such measurements allow the analysis of the system’s heat flow through the network, which showed that losses exist, some areas. The results demonstrate successfully that the temperature and flow changes deserve more detailed and fixed monitoring in specific areas to help the user decide the optimum measuring point.