The Production of Isophorone
- Isophorone is a technically important compound used as a high-boiling-point solvent for coatings, adhesives, etc., and it is used as a starting material for various valuable compounds, including isophorone diisocyanate, a precursor for polyurethanes. For over 80 years, isophorone has been synthesized via base-catalyzed self-condensation of acetone. This reaction has a complex reaction mechanism with numerous possible reaction steps including the formation of isophorone, triacetone dialcohol, and ketonic resins. This review provides an overview of the different production processes of isophorone in liquid- and vapor-phase and reviews the literature-reported selectivity toward isophorone achieved using different reaction parameters and catalysts.
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| Author: | Timm Ruther, Marc-André Müller, Werner Bonrath, Matthias Eisenacher |
|---|---|
| URN: | urn:nbn:de:hbz:832-epub4-21208 |
| DOI: | https://doi.org/10.3390/encyclopedia3010015 |
| ISSN: | 2673-8392 |
| Parent Title (English): | Encyclopedia |
| Publisher: | MDPI |
| Editor: | George Z. Kyzas, Raffaele Barretta |
| Document Type: | Article |
| Language: | English |
| Date of first Publication: | 2023/02/22 |
| Date of Publication (online): | 2023/04/17 |
| GND-Keyword: | Katalyse |
| Tag: | Base-Catalyzed; Catalysis; Delf-Condensation; Isophorone; Scetone |
| Volume: | 3 |
| Issue: | 1 |
| Page Number: | 21 |
| Institutes: | Angewandte Naturwissenschaften (F11) |
| Dewey Decimal Classification: | 500 Naturwissenschaften und Mathematik |
| Open Access: | Open Access |
| DeepGreen: | DeepGreen |
| Licence (German): |  Creative Commons - CC BY - Namensnennung 4.0 International |