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This paper presents a series of flow and temperature measurements on the principal heat network of :metabolon in Lindlar, Germany. These measurements intend to show the behaviour of the system on specific production areas of :metabolon for future monitoring and optimisation purposes. Such measurements allow the analysis of the system’s heat flow through the network, which showed that losses exist, some areas. The results demonstrate successfully that the temperature and flow changes deserve more detailed and fixed monitoring in specific areas to help the user decide the optimum measuring point.
The utilization of roadside-green-cuttings (grass) for anaerobic digestion increases provides an additional possible source of organic waste for use as a renewable energy source. Grass can be used as a substrate to increase biogas yield. Nevertheless, the anaerobic digestion of this kind of waste can be limited due to the fact that it could be contaminated with heavy metals, in particular from traffic emissions and industrial activity. For this reason the biogas production of grass from a busy road was assessed. Samples of roadside-grass were washed with an organosulphide, which is used for the removal of heavy metals from wastewater.
A comparison of the anaerobic digestion of washed and unwashed roadside grass was performed. Results showed that the anaerobic digestion of the unwashed grass was much more effective than the washed grass. A second experiment was carried out and co-fermentation of manure and farm-grass was prepared for anaerobic digestion. Lead was added in the concentrations 500, 1000 and 2000 mg Pb2+/kg. The results showed that the higher the lead concentration, the lower the inhibition of the biogas yield. The grass could be acting as phytoremediator for high lead concentrations. The grass could contain organic compounds, which can as-similate heavy metals.
Anaerobic Digestion of spent grains: Potential use in small-scale Biogas Digesters in Jos, Nigeria
(2014)
In order to ascertain biogas yield potential and applicability of spent grains (SG)1 in small-scale biogas production, laboratory batch fermentation was performed with various masses of dry and wet SG using sewage sludge (SS)2 and digested maize silage (DMs) 3 as inoculums. Different volumes of biogas and CH4 were measured with higher volumes observed for batch fermentation with DMs in com-parison to those produced by SS. Results from the study reveals minimum biogas yield of 118.10 L/kg
VS and maximum yields of 769.46 L/kg VS, which are indicative of the possible use of SG for domestic biogas production in Jos, Nigeria. The study established the fact that the use of both dry and wet SG results in the yield of a useful amount of biogas having 40 - 60 % CH4 content depending on the inoculum and amount of volatile solids present. Using the parameters of dry matter and volatile solids contents analysed for SG and DMs, it was estimated that a reactor volume of 6.47 m3 would be capable of meeting the daily cooking needs of rural households in Jos, Nigeria.
Comparative analysis of non-natural acceptor glucosylation with sucrase enzymes of family GH 70
(2019)
Mutan- and alternansucrase were analyzed for their non-natural glucosylation potential with catecholic compounds caffeic acid and nordihydroguaiaretic acid (NDGA) as well as with non-catecolic p-coumaric acid and umbellic acid. Mutansucrase accepted both catecholic substrates and high glucosylation yields of 92 % with caffeic acid and 81 % with NDGA were obtained. The enzyme showed a clear regio-preference for the catechol 4-OH, which corresponds to findings from our previous work with Leuconostoc and Weissella derived glucansucrases. The substrate spectrum of the alternansucrase was broader and all substrates were successfully glucosylated with a preference for the catechols. Interestingly alternansucrase possessed a different regio-specificity. With caffeic acid the 3-O-α-D-glucoside was the major product. A similar substrate spectrum and regioselectivity pattern was observed in previous glucansucrase screenings only with glucansucrase from strain Weissella beninensis DSM 22752. Therefore it may be concluded that the W. beninensis enzyme is an alternansucrase type enzyme as well.
Modern industrial biomass combustion plants are regulated by the power and/or combustion control. In this process, the implemented sensors collect the relevant measured data. The aim is to achieve ideal combustion with optimum efficiency and to minimize gas emissions. For this purpose, a group within the research project Metabolon developed new regulatory procedures in order to record the combustion process of a biomass combustion plant using a webcam. The recordings were evaluated automatically and were used for a better monitoring of the process. In addition, the webcam-based method aims, among other things, to provide private homes with a cost-effective variant as an alternative to industrial system solutions.
The introduction of Feed-in tariffs in the German Renewable Energy Act (EEG) fuelled the growth of anaerobic digestion (AD) industry making Germany the country with highest number of operational AD plants. However, the rapid expansion of AD industry resulted in some unwanted side-effects such as food vs fuel debate, increased prices for electricity and the temporal mismatch between supply and demand of electricity grid. Subsequent amendments in EEG has tried to address some of these issues by reduction in Feed-in tariffs, introduction of a cap on cereal based feedstocks and providing premium for energy production in accordance with market demand. Furthermore, the Feed-in tariffs which were introduced for 20 years are soon going to expire. The changes in legal and political discourse is soon going to introduce some new challanges to the AD industry. This paper has discussed some of these challanges and their potential solutions.
The electricity network is undergoing a change due to reducing costs for renewable energy sources. Subsidy programs for renewable energy sources are changing and the funding available is being reduced. This will have an impact on anaerobic digestion which in some cases may struggle financially. Overfeeding is one of the most common mechanisms of inhibition in the process, and by shifting to intermittent feeding for on-demand production, this change will provide more information about the digestion process and could be used to detect the beginning of inhibition due to overfeeding. This paper discusses the shift towards intermittent production and how this change can be used to monitor the anaerobic digestion process.
The synthesis of 17-hydroxy-oleic acid based oligomeric esters was investigated with immobilized Pseudozyma antarctica Lipase B and hexanediol as co-substrate. The effects of different reaction parameters on velocity and product composition at equilibrium conditions were analyzed. The synthesis of oleic acid esters was used as a reference system for initial evaluation of reaction parameters. The reaction with oleic acid and hexanediol was fastest at an enzyme concentration of 5% at 60 °C and high conversions of > 90 % were achieved in non-polar solvents in the presence of molecular sieves. In heptane an oleic acid conversion of 96 % was reached with a final diester to monoester ratio of > 4:1. In syntheses trials with 17-hydroxy-oleic acid the formation of oligomers was verified with GPC, however; conversion was generally lower than with oleic acid. Removal of hydroxyl fatty acid monomers and dimers and the formation ester functionalities could be verified by GC analysis. An increase of the degree of oligomerization was observed simultaneously by GPC analysis. The number-average molecular weight was around 1400 in the best trials corresponding to a degree of oligomerization of around 4 units of hydroxyl-fatty acid attached to a hexanediol core. Though transformations were not complete, the final oligomer size was in the lower range of polyester diols used for polyurethane manufacturing.
In this paper a closed-loop substrate feed control for agricultural biogas plants is proposed. In this case, multi-objective nonlinear model predictive control is used to control composition and amount of substrate feed to optimise the economic feasibility of a biogas plant whilst assuring process stability. The control algorithm relies on a detailed biogas plant simulation model using the Anaerobic
Digestion Model No. 1. The optimal control problem is solved using the state-of-the-art multi-objective optimization method SMS-EGO. Control performance is evaluated by means of a set point tracking problem in a noisy environment.
Results show, that the proposed control scheme is able to keep the produced electrical energy close to a set point with an RMSE of 0.9 %, thus maintaining optimal biogas plant operation.
In the last few decades raw material molasses, used in large scale fermentations in the production of bioethanol, citric acid, (baker´s) yeast and yeast extracts, has become more and more expensive. That is why agro-industrial wastes have become an interesting alternative. They are being produced in large volumes every day and represent a serious environmental problem considering its high organic content. The present contribution aims to demonstrate how waste products of wine production can be employed as substrate in bioethanol production. Cultivation of yeast and bioethanol production on molasses and grape pomace extract was studied in flasks in laboratory scale. This work should be regarded as an example of integrated sustainability which demonstrates how the waste from one industrial process is used as feedstock for another.